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Benzo(a)pyrene and Hexachlorobenzene
Stakeholders Forum - Toronto,
Ontario
May 14, 2003
Hexachlorobenzene/Benzo(a)pyrene Workgroup Meeting
Workgroup Leaders: U.S. Workgroup Co-chair: Steve Rosenthal Canadian Workgroup Co-chair: Tom Tseng
1.0 Pesticides
Dale Phenicie reported that work is still underway on
gathering information from U.S. manufacturers on the quantities of
HCB found as trace contamination in some pest control products. In
view of product confidentially, the object of the work is to come-up
with an overall aggregate HCB quantity contained in these applied
products. Although information gathered to date is still incomplete,
as some manufacturers have yet to respond, it suggests that trace
contaminant levels are much lower than permitted by regulation, and
that the HCB quantity in pest control products in the U.S. may be in
the order of 600 lbs/year rather than the 2500 lbs/year permitted.
These figures assume an HCB volatilization rate from applied pest
control products of 100%. It is recognized that a lower
volatilization rate of 8% would place HCB releases in the 25
lbs/year range.
For the Canadian side of the Great Lakes basin (Ontario), Judy Shaw has provided the workgroup with an HCB release estimate of 77 kg for 2002 obtained from Canada's Pest Management Regulatory Agency. A number of issues have been identified with respect to this estimate, such as whether this is a National or Ontario number and whether maximum permitted HCB levels or actual product content levels were used to derive it. The workgroup is working with Judy to resolve this matter.
Bob Bailey noted that the 600 lbs/yr of HCB currently estimated for the pesticide sector is about 50% of that identified as being released from facilities reporting to the U.S. Toxic Release Inventory in 2000, and that many other small combustion sources are also contributing to HCB loadings, along with a major world-wide ongoing release from fields treated with pesticides (estimated at 100 tons/year). In view of the gross quantities boiling off treated fields, Bob suggested that the current HCB releases associated with pesticide use in the U.S. are not significant. It was also pointed out that Great Lake HCB levels are in equilibrium with air flow, and that levels in most fish are falling below detection limits.
Action Item - Dale Phenicie and Judy Shaw are to report back at the next Binational Toxic Strategy meeting in December 2003 in Chicago on HCB product content/usage/release estimates for the pesticide sector.
2.0 Scrap Tires
Michael Blumenthal with the Rubber Manufacturers Association
(RMA) presented detailed information on scrap tire management in the
Great Lakes Basin. Of the estimated 300,000,000 tires in stockpiles
in the U.S., 150,000,000 or 50% are located in Great Lake States
(Michigan, Indiana, Ohio, Pennsylvania, and New York), i.e. the
largest in the basin being New York State with a stockpile of
50,000,000. Scrap tire programs are state driven and a variety of
actions and regulations have been or are being enacted aimed at
cleaning up old scrap tire piles and encouraging recycle markets.
For example, Michigan has in place a collection fee and a strong
market incentive for scrap rubber, while New York is about to enact
legislation for a fee to fund scrap tire clean up efforts. To help
provide technical assistance, RMA has training courses on fire
prevention.
Steven Rosenthal mentioned that Paul Ruesch with U.S. EPA Region 5 has developed a scrap tire site inventory using GIS mapping, pinpointing all storage sites; and he is now looking at putting together a best practical management document for abatement of scrap tire piles. Over the last 10 years, Michael mentioned that there have been in the order of 20 major tire fires, most due to arson.
From the RMA perspective, one of the major elements in achieving a satisfactory management program is a consumer disposal fee system, a system not in place in Ontario at the present time. The Rubber Association of Canada and the RMA work closely on rubber recycling activities, and negotiations are underway with the Ontario Ministry of the Environment concerning its new proposed scrap tire management program. The contact with the Rubber Association of Canada is the President Glenn Maidment 905-814-1714 (glenn@rubberassociation.ca).
Michael suggested that RMA, and affiliates like the Rubber Association of Canada, are prepared to work with and support Binational Toxic Strategy efforts aimed at getting rid of the scrap tire stockpiles. A number of meetings with state scrap tire regulators, fire officials, and others have been held over the years and such meeting opportunities may present a forum for pursuing BTS issues on scrap tire pile abatement. A project that may be worth pursuing is to develop markets to use tires as a fuel.
Resource Needs - About $25,000 is needed to put the location of all scrap tire piles on a GIS map, develop and print a best practices guidebook for stockpile mitigation, and develop a training presentation for delivery to states and counties at solid waste conferences. This is needed to successfully implement a Scrap Tire Outreach Plan.
3.0 Coke Ovens
David Ailor provided an update on the steel making coking
sector:
- Six coke batteries closed in 2002 (one in Chicago, one in Ohio, and 4 in Utah) and further closures under consideration;
- US EPA finalized rules for wastewater discharges from iron and steel facilities in October 2002 and these rules apply in part to B(a)P releases;
- US EPA finalized MACT standards for coke oven battery stacks in April 2003. (These standards reflect the performance of the best plants in the industry)
- US EPA residual risk assessment continues on coke making operations, which have implemented MACT standards, to determine if more stringent standards are require to provide an "ample margin of safety". A final rule is expected to come into effect in the next year and a half. Coke oven batteries at four plants would be impacted by these residual risk standards;
- With respect to US EPA draft AP-42 Section 12.2 (Coke Production), the Coke Oven Environmental Task Force (formed by the American Iron and Steel Institute and the American Coke and Coal Chemicals Institute) has not heard from the US EPA since the task force forwarded their comments on the draft in November 2001. (AP-42 is a listing of emission factors for various pollutants used to estimate releases.)
General comments were make to the effect that B(a)P reduction in the U.S. steel sector from 1993 to present has been due mainly to rules and regulations, as compared to the steel sector in China where rules and regulations are lax and gross emissions are still occurring.
4.0 Residential Wood Combustion
Jim Collins gave a slide presentation (see Appendix 1) on
the 2002- 2003 Burn it Smart wood heating education Campaign, a
national Canadian initiative by a multi-stakeholder committee led by
Natural Resources Canada. The general aim of the campaign is reduce
wood smoke emissions by educating consumers through free
community-based workshops on the safety and health aspects of
residential wood burning, and the various wood heating options
including the introduction of highly efficient advanced combustion
technology.
By the end of March 2003, over 300 workshops were held across Canada in 200 communities; 60 workshops in 32 communities in Ontario. Many workshops featured a demonstration "burn" trailer that visually shows the difference between old combustion technology and low-emissions, advanced combustion technology.
Environment Canada - Ontario Region is planning to continue the Burn it Smart Campaign in 2003-2004 with more workshops across Ontario. It was emphasized that good workshop speakers were key to a successful Campaign.
Tex McLeod commented that most people attending the workshops are environmentally conscious, but many do not believe wood stoves pollute, and that there is still merit in holding these workshops and getting the message out.
The issue of indoor air quality in households using wood stoves was also identified as a concern, particularly to children's health, and how to get this item on an agenda. It was noted that Health Canada has been a contributor to the Burn it Smart Campaign.
Steven Rosenthal stated that work in the residential wood combustion sector is behind in the U.S. and that planning is needed in this area to see if projects like the Burn it Smart Campaign can be replicated in the U.S. The cost of one workshop is, about $1500. Resource Needs- about $50,000 is needed to start a "Burn-it Smart " type campaign in the U.S.
The following Handouts were provided (a) A Natural Resources "A Guide to Residential Wood Heating", (b) brochures and fact sheets from the Burn it Smart campaign.
5.0 Vehicle Emissions
Cindy Yang presented draft data on vehicle emissions in
Ontario developed using the most up-to-date US EPA and Environment
Canada emission factors (see Appendix 2). With respect to B(a)P, the
updated release is expected to replace the current Ontario estimate
in the Binational Toxic Strategy inventory. The previous estimate
was based on emission factors which did not take into account B(a)P
present in both the gas and particle phases, and thus,
underestimated releases. It should be noted that the updated
inventory data is for on-road vehicles in Ontario, and does not
include releases from marine, rail and air transportation sectors.
In 2001, B(a)P release from the motor vehicle sector was estimated at 6% of the total Ontario release, up from 3% in 1988; while PAH release was 6% in 2001 up from 4% in 1988.
Aside from PAHs and B(a)P, releases of other GLBTS substances from the motor vehicle sector were also assessed, including HCB, OCS, mercury, dioxins/furans and cadmium. HCB and OCS releases are considered to be insignificant, while some uncertainties are associated with the factors used to derive the mercury, cadmium and dioxin/furan estimates.
Next steps:
- Meet with the Canadian Vehicle Manufacturers' Association to review and confirm estimates for their sector, and discuss reduction alternatives;
- Continue follow up with US EPA to obtain further update on emission factors; and
- Conduct study on motor vehicle PAH emissions in Canada.
Discussion followed on the need for a concise strategy to reduce the use of private vehicles and to improve public transportation; as well as, to the fact that a clean air strategy for vehicles does exist and that vehicle issues should be tied to such efforts.
6.0 General Comments
Major B(a)P releases from the petroleum refining and
aluminum manufacturing sectors have all but disappeared from the BTS
inventory; and releases from coke making are on a downward trend,
while residential wood combustion now appears to be the predominant
source. B(a)P air quality in the Great Lakes shows little
improvement, however, which suggests that other sources, presently
unaccounted for, may be responsible. This highlights the need for
addition investigative work, such as back trajectory analyses, to
help pinpoint remaining sources.
With respect to HCB, the major issue still remains the generation of more accurate release numbers for the pesticide sector. Other areas for inventory improvement involve working with individual companies reporting HCB releases and looking at the global HCB balance.
Linkage with the Commission for Environmental Cooperation of North America (CEC) needs to be explored to see if opportunities exist to engage with CEC in moving forward on HCB/B(a)P work group issues.
Participant's Rooster
| Name | Organization | Telephone | |
|
Ailor, David |
American Coke and Coal Chemicals |
(202) 452-1140 | Dailor@accci.org |
| Alvarado, Leonor | CICH | (613) 230-8838 ex 243 | lalvarado@cich.ca |
| Bailey, Bob | Bailey Associates | (989) 835-3410 | Bob.Bailey@tm.net |
| Blumenthal, Michael | Rubber Manufacturers Association | (202) 682-4882 | Michael@rma.org |
| Collins, Jim | Environment Canada, Ontario Region | (416) 739-5801 | james.collins@ec.gc.ca |
| Crouch, John | Hearth, Patio, and Barbecue Association | (916) 536-2390 | Crouch@hpba.org |
| Hogg, Darryl | Contractor, Environment Canada | (416) 483-6563 | hoggrd@rogers.com |
| McLeod, Tex | Hearth, Patio and Barbecue Association of Canada | (416) 921-5501 | tex@idirect.com |
| Michajluk, Shawn | Environment Canada, Ontario Region | (416) 739-5888 | hawn.michajluk@ec.gc.ca |
| Phenicie, Dale | Council of Great Lake Industries | (770) 487-7585 | DKPhenicie@Mindspring.com |
| Risotto, Steve | Halogenated Solvents Industry Alliance, Inc. | (703) 741-5780 | Srisotto@hsia.org |
| Rosenthal, Steve | USEPA Region 5 | (312) 886-6052 | osenthal.Steven@epamail.epa.gov |
| Tseng, Tom | Environment Canada, Ontario Region | (416) 739-5853 | tom.tseng@ec.gc.ca |
| Yang, Cindy | Environment Canada, Ontario Region | (416) 739-4493 | Cindy.Yang@ec.gc.ca |
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