P @ - # @P # BP B `
P* v _ W v 2 2 ? @ - & " " & " " & & & & & " " " " " " " " " " & & & & & " " " " " " " " " " # 6 15 ppm S Precis # 6 15 ppm S Accura # 6 500 ppm S Preci # 6 500 ppm S Accur # 6 Ex 15 ppm S # 6 Ex 15 ppm Acc. # 6 Ex 500 ppm Pre # 6 Ex 500 ppm Acc ^ ^15 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-0308 Expires 12/31/2011] 'Test Method "Name of Method: "Organization ID No.: 'Laboratory Identification "Laboratory Name: "Laboratory Street Address: "Laboratory City: "Laboratory State: "Laboratory Zip code: "Laboratory Contact Person: % "Laboratory Contact Phone Number ) "Laboratory Contact Facsimile Number ' "Laboratory Contact E-mail Address 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) '15 ppm Sulfur Precision Criterion - a standard deviation less than 0.72 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 5 to 15 ppm. The 20 results must be a series of tests with a sequential record of the analyses and no omissions. Samples or results may be excluded only if for valid reason under good laboratory practices & records are maintained for reason of exclusion. / 'Is 15 ppm Sulfur Precision Criterion Met? ( 8 & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING ףp= ?PASSED FAILED ;;;; REQUIRED DATA MISSING ^standard deviation ( C P & P REQUIRED DATA MISSING & ; REQUIRED DATA MISSING + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ( 6 h DATA REQUIRED IN CELL D20 OK ; DATA REQUIRED IN CELL D20 ( 6 DATA REQUIRED IN CELL D21 OK ; DATA REQUIRED IN CELL D21 ( 6 DATA REQUIRED IN CELL D22 OK ; DATA REQUIRED IN CELL D22 ( 6 DATA REQUIRED IN CELL D23 OK ; DATA REQUIRED IN CELL D23 ( 6 DATA REQUIRED IN CELL D24 OK ; DATA REQUIRED IN CELL D24 ( 6 DATA REQUIRED IN CELL D25 OK ; DATA REQUIRED IN CELL D25 ( 6 DATA REQUIRED IN CELL D26 OK ; DATA REQUIRED IN CELL D26 ( 6 , DATA REQUIRED IN CELL D27 OK ; DATA REQUIRED IN CELL D27 ( 6 H DATA REQUIRED IN CELL D28 OK ; DATA REQUIRED IN CELL D28 ( 6 d DATA REQUIRED IN CELL D29 OK ; DATA REQUIRED IN CELL D29 ( 6 DATA REQUIRED IN CELL D30 OK ; DATA REQUIRED IN CELL D30 ( 6 DATA REQUIRED IN CELL D31 OK ; DATA REQUIRED IN CELL D31 ( 6 DATA REQUIRED IN CELL D32 OK ; DATA REQUIRED IN CELL D32 ( 6 DATA REQUIRED IN CELL D33 OK ; DATA REQUIRED IN CELL D33 ( 6 ! ! DATA REQUIRED IN CELL D34 OK ; ! DATA REQUIRED IN CELL D34 ( 6 " " DATA REQUIRED IN CELL D35 OK ; " DATA REQUIRED IN CELL D35 ( 6 # ( # DATA REQUIRED IN CELL D36 OK ; # DATA REQUIRED IN CELL D36 ( 6 $ D $ DATA REQUIRED IN CELL D37 OK ; $ DATA REQUIRED IN CELL D37 ( 6 % ` % DATA REQUIRED IN CELL D38 OK ; % DATA REQUIRED IN CELL D38 ( 6 & | & DATA REQUIRED IN CELL D39 OK ; & DATA REQUIRED IN CELL D39 ^ ^15 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0308 Expires 12/31/2011] 'Test Method "Name of Method: ( "Organization ID No.: ( 'Laboratory Identification "Laboratory Name: ( "Laboratory Street Address: ( "Laboratory City: ( "Laboratory State: ( "Laboratory Zip code: ( "Laboratory Contact Person: ( % "Laboratory Contact Phone Number ( ) "Laboratory Contact Facsimile Number ( ' "Laboratory Contact E-mail Address ( 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) '1 to 10 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 1 to 10 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 0.54 ppm. Individual test results shall be compensated for any known chemical interferences. '10 to 20 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 10 to 20 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 0.54 ppm. Individual test results shall be compensated for any known chemical interferences. % ^Accuracy Criterion for 1-10 ppm & ^Accuracy Criterion for 10-20 ppm ! ^gravimetric sulfur standard ! ^gravimetric sulfur standard 0 'Is 1-10 ppm Sulfur Accuracy Criterion Met? ( ~ " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING HzG?PASSED FAILED ;;; REQUIRED DATA MISSING 1 'Is 10-20 ppm Sulfur Accuracy Criterion Met? ( ~ " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING HzG?PASSED FAILED ;;; REQUIRED DATA MISSING ^Arithmetic Average (ppm) ( C " P REQUIRED DATA MISSING " ; REQUIRED DATA MISSING ^Arithmetic Average (ppm) ( C " P REQUIRED DATA MISSING " ; REQUIRED DATA MISSING ) ^Vendor Name of Gravimetric Standard ) ^Vendor Name of Gravimetric Standard 7 ^Lot Identification Number of Gravimetric Standard # ^Concentration QC Check on ARV 7 ^Lot Identification Number of Gravimetric Standard # ^Concentration QC Check on ARV B ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm) ( h @ ARV TOO LOW IN CONCENTRATION ARV TOO HIGH IN CONCENTRATION OK ;; ! ARV TOO LOW IN CONCENTRATION B ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm) ( h ARV TOO LOW IN CONCENTRATION ARV TOO HIGH IN CONCENTRATION OK ;; ! ARV TOO LOW IN CONCENTRATION K ^Difference between Arithmetic Average and ARV of Gravimetric Standard ( Q 8 REQUIRED DATA MISSING REQUIRED DATA MISSING !; REQUIRED DATA MISSING K ^Difference between Arithmetic Average and ARV of Gravimetric Standard ( Q P REQUIRED DATA MISSING REQUIRED DATA MISSING !; REQUIRED DATA MISSING + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ( 6 h DATA REQUIRED IN CELL D26 OK ; DATA REQUIRED IN CELL D26 ( 6 DATA REQUIRED IN CELL J26 OK ; DATA REQUIRED IN CELL J26 ( 6 DATA REQUIRED IN CELL D27 OK ; DATA REQUIRED IN CELL D27 ( 6 DATA REQUIRED IN CELL J27 OK ; DATA REQUIRED IN CELL J27 ( 6 DATA REQUIRED IN CELL D28 OK ; DATA REQUIRED IN CELL D28 ( 6 DATA REQUIRED IN CELL J28 OK ; DATA REQUIRED IN CELL J28 ( 6 DATA REQUIRED IN CELL D29 OK ; DATA REQUIRED IN CELL D29 ( 6 , DATA REQUIRED IN CELL J29 OK ; DATA REQUIRED IN CELL J29 ( 6 H DATA REQUIRED IN CELL D30 OK ; DATA REQUIRED IN CELL D30 ( 6 d DATA REQUIRED IN CELL J30 OK ; DATA REQUIRED IN CELL J30 ( 6 DATA REQUIRED IN CELL D31 OK ; DATA REQUIRED IN CELL D31 ( 6 DATA REQUIRED IN CELL J31 OK ; DATA REQUIRED IN CELL J31 ( 6 DATA REQUIRED IN CELL D32 OK ; DATA REQUIRED IN CELL D32 ( 6 DATA REQUIRED IN CELL J32 OK ; DATA REQUIRED IN CELL J32 ( 6 DATA REQUIRED IN CELL D33 OK ; DATA REQUIRED IN CELL D33 ( 6 DATA REQUIRED IN CELL J33 OK ; DATA REQUIRED IN CELL J33 ( 6 ! ( ! DATA REQUIRED IN CELL D34 OK ; ! DATA REQUIRED IN CELL D34 ( 6 ! D ! DATA REQUIRED IN CELL J34 OK ; ! DATA REQUIRED IN CELL J34 ( 6 " ` " DATA REQUIRED IN CELL D35 OK ; " DATA REQUIRED IN CELL D35 ( 6 " | " DATA REQUIRED IN CELL J35 OK ; " DATA REQUIRED IN CELL J35 a ^500 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-00308 Expires 12/31/2011] 'Test Method "Name of Method: "Organization ID No.: 'Laboratory Identification "Laboratory Name: "Laboratory Street Address: "Laboratory City: "Laboratory State: "Laboratory Zip code: "Laboratory Contact Person: % "Laboratory Contact Phone Number ) "Laboratory Contact Facsimile Number ' "Laboratory Contact E-mail Address 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) '500 ppm Sulfur Precision Criterion - a standard deviation less than 0.72 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 5 to 15 ppm. The 20 results must be a series of tests with a sequential record of the analyses and no omissions. Samples or results may be excluded only if for valid reason under good laboratory practices & records are maintained for reason of exclusion. 0 'Is 500 ppm Sulfur Precision Criterion Met? ( & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING \(\#@PASSED FAILED ;;;; REQUIRED DATA MISSING ^standard deviation ( C & P REQUIRED DATA MISSING & ; REQUIRED DATA MISSING + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ( 6 DATA REQUIRED IN CELL D20 OK ; DATA REQUIRED IN CELL D20 ( 6 DATA REQUIRED IN CELL D21 OK ; DATA REQUIRED IN CELL D21 ( 6 DATA REQUIRED IN CELL D22 OK ; DATA REQUIRED IN CELL D22 ( 6 DATA REQUIRED IN CELL D23 OK ; DATA REQUIRED IN CELL D23 ( 6 8 DATA REQUIRED IN CELL D24 OK ; DATA REQUIRED IN CELL D24 ( 6 T DATA REQUIRED IN CELL D25 OK ; DATA REQUIRED IN CELL D25 ( 6 p DATA REQUIRED IN CELL D26 OK ; DATA REQUIRED IN CELL D26 ( 6 DATA REQUIRED IN CELL D27 OK ; DATA REQUIRED IN CELL D27 ( 6 DATA REQUIRED IN CELL D28 OK ; DATA REQUIRED IN CELL D28 ( 6 DATA REQUIRED IN CELL D29 OK ; DATA REQUIRED IN CELL D29 ( 6 DATA REQUIRED IN CELL D30 OK ; DATA REQUIRED IN CELL D30 ( 6 DATA REQUIRED IN CELL D31 OK ; DATA REQUIRED IN CELL D31 ( 6 DATA REQUIRED IN CELL D32 OK ; DATA REQUIRED IN CELL D32 ( 6 4 DATA REQUIRED IN CELL D33 OK ; DATA REQUIRED IN CELL D33 ( 6 ! P ! DATA REQUIRED IN CELL D34 OK ; ! DATA REQUIRED IN CELL D34 ( 6 " l " DATA REQUIRED IN CELL D35 OK ; " DATA REQUIRED IN CELL D35 ( 6 # # DATA REQUIRED IN CELL D36 OK ; # DATA REQUIRED IN CELL D36 ( 6 $ $ DATA REQUIRED IN CELL D37 OK ; $ DATA REQUIRED IN CELL D37 ( 6 % % DATA REQUIRED IN CELL D38 OK ; % DATA REQUIRED IN CELL D38 ( 6 & & DATA REQUIRED IN CELL D39 OK ; & DATA REQUIRED IN CELL D39 ^ ^500 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0308 Expires 12/31/2011] 'Test Method "Name of Method: ( "Organization ID No.: ( 'Laboratory Identification "Laboratory Name: ( "Laboratory Street Address: ( "Laboratory City: ( "Laboratory State: ( "Laboratory Zip code: ( "Laboratory Contact Person: ( % "Laboratory Contact Phone Number ( ) "Laboratory Contact Facsimile Number ( ' "Laboratory Contact E-mail Address ( 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) '100 to 200 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 100 to 200 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 7.26 ppm. Individual test results shall be compensated for any known chemical interferences. '400 to 500 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 400 to 500 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 7.26 ppm. Individual test results shall be compensated for any known chemical interferences. ( ^Accuracy Criterion for 100-200 ppm ( ^Accuracy Criterion for 400-500 ppm ! ^gravimetric sulfur standard ! ^gravimetric sulfur standard 3 'Is 100-200 ppm Sulfur Accuracy Criterion Met? ( ~ " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING ףp= @PASSED FAILED ;;; REQUIRED DATA MISSING 3 'Is 400-500 ppm Sulfur Accuracy Criterion Met? ( ~ " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING ףp= @PASSED FAILED ;;; REQUIRED DATA MISSING ^Arithmetic Average (ppm): ( C ( " P REQUIRED DATA MISSING " ; REQUIRED DATA MISSING ^Arithmetic Average (ppm) ( C @ " P REQUIRED DATA MISSING " ; REQUIRED DATA MISSING * ^Vendor Name of Gravimetric Standard: ) ^Vendor Name of Gravimetric Standard 8 ^Lot Identification Number of Gravimetric Standard: # ^Concentration QC Check on ARV 7 ^Lot Identification Number of Gravimetric Standard # ^Concentration QC Check on ARV C ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm): ( h X ARV TOO LOW IN CONCENTRATION 2 ARV TOO HIGH IN CONCENTRATION OK ;; ! ARV TOO LOW IN CONCENTRATION B ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm) ( h x d ARV TOO LOW IN CONCENTRATION } ARV TOO HIGH IN CONCENTRATION OK ;; ! ARV TOO LOW IN CONCENTRATION L ^Difference between Arithmetic Average and ARV of Gravimetric Standard: ( Q REQUIRED DATA MISSING REQUIRED DATA MISSING !; REQUIRED DATA MISSING K ^Difference between Arithmetic Average and ARV of Gravimetric Standard ( Q REQUIRED DATA MISSING REQUIRED DATA MISSING !; REQUIRED DATA MISSING + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ( 6 DATA REQUIRED IN CELL D26 OK ; DATA REQUIRED IN CELL D26 ( 6 DATA REQUIRED IN CELL J26 OK ; DATA REQUIRED IN CELL J26 ( 6 DATA REQUIRED IN CELL D27 OK ; DATA REQUIRED IN CELL D27 ( 6 DATA REQUIRED IN CELL J27 OK ; DATA REQUIRED IN CELL J27 ( 6 8 DATA REQUIRED IN CELL D28 OK ; DATA REQUIRED IN CELL D28 ( 6 T DATA REQUIRED IN CELL J28 OK ; DATA REQUIRED IN CELL J28 ( 6 p DATA REQUIRED IN CELL D29 OK ; DATA REQUIRED IN CELL D29 ( 6 DATA REQUIRED IN CELL J29 OK ; DATA REQUIRED IN CELL J29 ( 6 DATA REQUIRED IN CELL D30 OK ; DATA REQUIRED IN CELL D30 ( 6 DATA REQUIRED IN CELL J30 OK ; DATA REQUIRED IN CELL J30 ( 6 DATA REQUIRED IN CELL D31 OK ; DATA REQUIRED IN CELL D31 ( 6 DATA REQUIRED IN CELL J31 OK ; DATA REQUIRED IN CELL J31 ( 6 DATA REQUIRED IN CELL D32 OK ; DATA REQUIRED IN CELL D32 ( 6 4 DATA REQUIRED IN CELL J32 OK ; DATA REQUIRED IN CELL J32 ( 6 P DATA REQUIRED IN CELL D33 OK ; DATA REQUIRED IN CELL D33 ( 6 l DATA REQUIRED IN CELL J33 OK ; DATA REQUIRED IN CELL J33 ( 6 ! ! DATA REQUIRED IN CELL D34 OK ; ! DATA REQUIRED IN CELL D34 ( 6 ! ! DATA REQUIRED IN CELL J34 OK ; ! DATA REQUIRED IN CELL J34 ( 6 " " DATA REQUIRED IN CELL D35 OK ; " DATA REQUIRED IN CELL D35 ( 6 " " DATA REQUIRED IN CELL J35 OK ; " DATA REQUIRED IN CELL J35 _ ^15 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-0308 Expires 12/31/2011] 'Test Method "Name of Method: s 'Total Sulfur in Liquid Aromatic Hydrocarbons and Their Derivatives by Oxidative and Electrochemical Detection "Organization ID No.: 'ASTM D 6428-99 'Laboratory Identification "Laboratory Name: ? 'USEPA National and Vehicle Fuels Emissions Laboratory/OAR "Laboratory Street Address: ( '2565 Plymouth Road, Mailcode AATSG "Laboratory City: 'Ann Arbor "Laboratory State: 'Michigan "Laboratory Zip code: % @. "Laboratory Contact Person: 'Joe Sopata % "Laboratory Contact Phone Number '202-343-9034 ) "Laboratory Contact Facsimile Number '202-343-2801 ' "Laboratory Contact E-mail Address 'sopata.joe@epa.gov 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) ^No '15 ppm Sulfur Precision Criterion - a standard deviation less than 0.72 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 5 to 15 ppm. The 20 results must be a series of tests with a sequential record of the analyses and no omissions. Samples or results may be excluded only if for valid reason under good laboratory practices & records are maintained for reason of exclusion. / 'Is 15 ppm Sulfur Precision Criterion Met? ( & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING ףp= ?PASSED FAILED ;;;; PASSED ^standard deviation ( `pBw? & + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ^######### % c% ' UUUUUU?% ( 6 DATA REQUIRED IN CELL D20 OK ; OK ^######### % c% ' ` `?% S ( 6 DATA REQUIRED IN CELL D21 OK ; OK ^######### % d% ' 88?% ( 6 DATA REQUIRED IN CELL D22 OK ; OK ^######### % @d% ' [[?% S ( 6 DATA REQUIRED IN CELL D23 OK ; OK ^######### % d% % ] % ( 6 DATA REQUIRED IN CELL D24 OK ; OK ^######### % e% ' q q?% ( 6 ( DATA REQUIRED IN CELL D25 OK ; OK ^######### % @e% ' 98?% S ( 6 0 DATA REQUIRED IN CELL D26 OK ; OK ^######### % e% ' UUUUUU?% S ( 6 8 DATA REQUIRED IN CELL D27 OK ; OK ^######### % f% ' q q ?% ( 6 @ DATA REQUIRED IN CELL D28 OK ; OK ^######### % @f% ' 88?% S ( 6 H DATA REQUIRED IN CELL D29 OK ; OK ^######### % f% ' ?% S ( 6 P DATA REQUIRED IN CELL D30 OK ; OK ^######### % f% ' q q ?% ( 6 X DATA REQUIRED IN CELL D31 OK ; OK ^######### % g% ' 88?% R ( 6 ` DATA REQUIRED IN CELL D32 OK ; OK ^######### % @g% % E % ( 6 h DATA REQUIRED IN CELL D33 OK ; OK ! ^######### % ! g% ' ! q q?% ! S ( 6 ! p ! DATA REQUIRED IN CELL D34 OK ; ! OK " ^######### % " g% ' " 98?% " R ( 6 " x " DATA REQUIRED IN CELL D35 OK ; " OK # ^######### % # h% ' # UUUUUU?% # S ( 6 # # DATA REQUIRED IN CELL D36 OK ; # OK $ ^######### % $ @h% ' $ q q ?% $ S ( 6 $ $ DATA REQUIRED IN CELL D37 OK ; $ OK % ^######### % % h% ' % 88?% % ( 6 % % DATA REQUIRED IN CELL D38 OK ; % OK & ^######### % & h% ' & ?% & ( 6 & & DATA REQUIRED IN CELL D39 OK ; & OK ^ ^15 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0308 Expires 12/31/2011] 'Test Method "Name of Method: ( n r Total Sulfur in Liquid Aromatic Hydrocarbons and Their Derivatives by Oxidative and Electrochemical Detection "Organization ID No.: ( ASTM D 6428-99 'Laboratory Identification "Laboratory Name: ( : > USEPA National and Vehicle Fuels Emissions Laboratory/OAR "Laboratory Street Address: ( \ # ' 2565 Plymouth Road, Mailcode AATSG "Laboratory City: ( Ann Arbor "Laboratory State: ( Michigan "Laboratory Zip code: ( }@ "Laboratory Contact Person: ( Joe Sopata % "Laboratory Contact Phone Number ( 202-343-9034 ) "Laboratory Contact Facsimile Number ( 202-343-2801 ' "Laboratory Contact E-mail Address ( sopata.joe@epa.gov 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) ^No '1 to 10 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 1 to 10 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 0.54 ppm. Individual test results shall be compensated for any known chemical interferences. '10 to 20 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 10 to 20 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 0.54 ppm. Individual test results shall be compensated for any known chemical interferences. % ^Accuracy Criterion for 1-10 ppm & ^Accuracy Criterion for 10-20 ppm ! ^gravimetric sulfur standard ! ^gravimetric sulfur standard 0 'Is 1-10 ppm Sulfur Accuracy Criterion Met? ( ~ " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING HzG?PASSED FAILED ;;; PASSED 1 'Is 10-20 ppm Sulfur Accuracy Criterion Met? ( ~ " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING HzG?PASSED FAILED ;;; PASSED ^Arithmetic Average (ppm) ( %C @ " ^Arithmetic Average (ppm) ( p= ף+@ " ) ^Vendor Name of Gravimetric Standard ^NIST ) ^Vendor Name of Gravimetric Standard ^NIST 7 ^Lot Identification Number of Gravimetric Standard ^ALDS45678 # ^Concentration QC Check on ARV 7 ^Lot Identification Number of Gravimetric Standard ^ALDS53478 # ^Concentration QC Check on ARV B ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm) % ( h @ ARV TOO LOW IN CONCENTRATION ARV TOO HIGH IN CONCENTRATION OK ;; OK B ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm) % ! ( h ARV TOO LOW IN CONCENTRATION ARV TOO HIGH IN CONCENTRATION OK ;; OK K ^Difference between Arithmetic Average and ARV of Gravimetric Standard ( |?5^? ! K ^Difference between Arithmetic Average and ARV of Gravimetric Standard ( Gz? ! + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ^######### % @w% ' UUUUUU?% S+ ( 6 DATA REQUIRED IN CELL D26 OK ; OK ^######### % w% ' UUUUUU?% ( 6 DATA REQUIRED IN CELL J26 OK ; OK ^######### % @w% ' ?% b ( 6 DATA REQUIRED IN CELL D27 OK ; OK ^######### % w% ' ?% ( 6 DATA REQUIRED IN CELL J27 OK ; OK ^######### % @w% % ] % ( 6 DATA REQUIRED IN CELL D28 OK ; OK ^######### % w% % ] % Ӓ ( 6 DATA REQUIRED IN CELL J28 OK ; OK ^######### % @w% ' UUUUUU?% ( 6 ( DATA REQUIRED IN CELL D29 OK ; OK ^######### % w% ' UUUUUU?% Ӵ ( 6 0 DATA REQUIRED IN CELL J29 OK ; OK ^######### % @w% ' ?% ( 6 8 DATA REQUIRED IN CELL D30 OK ; OK ^######### % w% ' ?% S ( 6 @ DATA REQUIRED IN CELL J30 OK ; OK ^######### % @w% % E % Q ( 6 H DATA REQUIRED IN CELL D31 OK ; OK ^######### % w% % E % ] ( 6 P DATA REQUIRED IN CELL J31 OK ; OK ^######### % @w% ' UUUUUU?% ( 6 X DATA REQUIRED IN CELL D32 OK ; OK ^######### % w% ' UUUUUU?% ( 6 ` DATA REQUIRED IN CELL J32 OK ; OK ^######### % @w% ' ?% S ( 6 h DATA REQUIRED IN CELL D33 OK ; OK ^######### % w% ' ?% S ( 6 p DATA REQUIRED IN CELL J33 OK ; OK ! ^######### % ! @w% % ! Q % ! Ӂ ( 6 ! x ! DATA REQUIRED IN CELL D34 OK ; ! OK ! ^######### % ! w% % ! Q % ! [ ( 6 ! ! DATA REQUIRED IN CELL J34 OK ; ! OK " ^######### % " @w% ' " ?% " S& ( 6 " " DATA REQUIRED IN CELL D35 OK ; " OK " ^######### % " w% ' " ?% " ( 6 " " DATA REQUIRED IN CELL J35 OK ; " OK ` ^500 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-0308 Expires 12/31/2011] 'Test Method "Name of Method: t 'Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry "Organization ID No.: 'ASTM D 2622-03 'Laboratory Identification "Laboratory Name: ? 'USEPA National and Vehicle Fuels Emissions Laboratory/OAR "Laboratory Street Address: ( '2565 Plymouth Road, Mailcode AATSG "Laboratory City: 'Ann Arbor "Laboratory State: 'Michigan "Laboratory Zip code: % @. "Laboratory Contact Person: 'Joe Sopata % "Laboratory Contact Phone Number '202-343-9034 ) "Laboratory Contact Facsimile Number '202-343-2801 ' "Laboratory Contact E-mail Address 'sopata.joe@epa.gov 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) ^No '500 ppm Sulfur Precision Criterion - a standard deviation less than 0.72 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 5 to 15 ppm. The 20 results must be a series of tests with a sequential record of the analyses and no omissions. Samples or results may be excluded only if for valid reason under good laboratory practices & records are maintained for reason of exclusion. 0 'Is 500 ppm Sulfur Precision Criterion Met? ( & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING & R REQUIRED DATA MISSING \(\#@PASSED FAILED ;;;; PASSED ^standard deviation ( @ & + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ^######### % c% ' UUUUUU?% IB( 6 DATA REQUIRED IN CELL D20 OK ; OK ^######### % c% ' ` `?% xC( 6 DATA REQUIRED IN CELL D21 OK ; OK ^######### % d% ' 88?% SE( 6 DATA REQUIRED IN CELL D22 OK ; OK ^######### % @d% ' [[?% F( 6 DATA REQUIRED IN CELL D23 OK ; OK ^######### % d% % ] % H( 6 DATA REQUIRED IN CELL D24 OK ; OK ^######### % e% ' q q?% ө@( 6 DATA REQUIRED IN CELL D25 OK ; OK ^######### % @e% ' 98?% YA( 6 DATA REQUIRED IN CELL D26 OK ; OK ^######### % e% ' UUUUUU?% _B( 6 DATA REQUIRED IN CELL D27 OK ; OK ^######### % f% ' q q ?% R ( 6 DATA REQUIRED IN CELL D28 OK ; OK ^######### % @f% ' 88?% =G( 6 DATA REQUIRED IN CELL D29 OK ; OK ^######### % f% ' ?% ( 6 DATA REQUIRED IN CELL D30 OK ; OK ^######### % f% ' q q ?% 1A( 6 DATA REQUIRED IN CELL D31 OK ; OK ^######### % g% ' 88?% !B( 6 DATA REQUIRED IN CELL D32 OK ; OK ^######### % @g% % E % 1E( 6 DATA REQUIRED IN CELL D33 OK ; OK ! ^######### % ! g% ' ! q q?% ! S,F( 6 ! ! DATA REQUIRED IN CELL D34 OK ; ! OK " ^######### % " g% ' " 98?% " QR ( 6 " " DATA REQUIRED IN CELL D35 OK ; " OK # ^######### % # h% ' # UUUUUU?% # M( 6 # # DATA REQUIRED IN CELL D36 OK ; # OK $ ^######### % $ @h% ' $ q q ?% $ K( 6 $ ( $ DATA REQUIRED IN CELL D37 OK ; $ OK % ^######### % % h% ' % 88?% % J( 6 % 0 % DATA REQUIRED IN CELL D38 OK ; % OK & ^######### % & h% ' & ?% & L( 6 & 8 & DATA REQUIRED IN CELL D39 OK ; & OK _ ^500 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0308 Expires 12/31/2011] 'Test Method "Name of Method: ( @ o s Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry "Organization ID No.: ( ASTM D 2622-03 'Laboratory Identification "Laboratory Name: ( : > USEPA National and Vehicle Fuels Emissions Laboratory/OAR "Laboratory Street Address: ( # ' 2565 Plymouth Road, Mailcode AATSG "Laboratory City: ( Ann Arbor "Laboratory State: ( , Michigan "Laboratory Zip code: ( }@ "Laboratory Contact Person: ( 8 Joe Sopata % "Laboratory Contact Phone Number ( D 202-343-9034 ) "Laboratory Contact Facsimile Number ( T 202-343-2801 ' "Laboratory Contact E-mail Address ( d sopata.joe@epa.gov 'Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) ^No '100 to 200 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 100 to 200 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 7.26 ppm. Individual test results shall be compensated for any known chemical interferences. '400 to 500 ppm Accuracy Criterion - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 400 to 500 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 7.26 ppm. Individual test results shall be compensated for any known chemical interferences. ( ^Accuracy Criterion for 100-200 ppm ( ^Accuracy Criterion for 400-500 ppm ! ^gravimetric sulfur standard ! ^gravimetric sulfur standard 3 'Is 100-200 ppm Sulfur Accuracy Criterion Met? ( ~ x " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING ףp= @PASSED FAILED ;;; PASSED 3 'Is 400-500 ppm Sulfur Accuracy Criterion Met? ( ~ " R REQUIRED DATA MISSING R@ REQUIRED DATA MISSING ףp= @PASSED FAILED ;;; PASSED ^Arithmetic Average (ppm): ( A߾b@ " ^Arithmetic Average (ppm) ( &S&@ " * ^Vendor Name of Gravimetric Standard: ^NIST ) ^Vendor Name of Gravimetric Standard ^NIST 8 ^Lot Identification Number of Gravimetric Standard: ^AMD4567 # ^Concentration QC Check on ARV 7 ^Lot Identification Number of Gravimetric Standard ^MNV5678 # ^Concentration QC Check on ARV C ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm): % % ( h ARV TOO LOW IN CONCENTRATION 2 ARV TOO HIGH IN CONCENTRATION OK ;; OK B ^Accepted Reference Value (ARV) of Gravimetric Standard (ppm) % } ( h d ARV TOO LOW IN CONCENTRATION } ARV TOO HIGH IN CONCENTRATION OK ;; OK L ^Difference between Arithmetic Average and ARV of Gravimetric Standard: ( ~@? ! K ^Difference between Arithmetic Average and ARV of Gravimetric Standard ( C>٬? ! + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result + ^Laboratory Test Identification Number ^Date ^Time ^Test Result (ppm) ( ^Data Entry QC Check on Test Result ^######### % @w% ' UUUUUU?% | ( 6 DATA REQUIRED IN CELL D26 OK ; OK ^######### % w% ' UUUUUU?% 0 ( 6 DATA REQUIRED IN CELL J26 OK ; OK ^######### % @w% ' ?% Ҧ ( 6 DATA REQUIRED IN CELL D27 OK ; OK ^######### % w% ' ?% R0 ( 6 DATA REQUIRED IN CELL J27 OK ; OK ^######### % @w% % ] % Qw ( 6 DATA REQUIRED IN CELL D28 OK ; OK ^######### % w% % ] % ( 6 DATA REQUIRED IN CELL J28 OK ; OK ^######### % @w% ' UUUUUU?% R ( 6 DATA REQUIRED IN CELL D29 OK ; OK ^######### % w% ' UUUUUU?% Ҳ0 ( 6 DATA REQUIRED IN CELL J29 OK ; OK ^######### % @w% ' ?% Qs ( 6 DATA REQUIRED IN CELL D30 OK ; OK ^######### % w% ' ?% o0 ( 6 DATA REQUIRED IN CELL J30 OK ; OK ^######### % @w% % E % % ( 6 DATA REQUIRED IN CELL D31 OK ; OK ^######### % w% % E % 0 ( 6 DATA REQUIRED IN CELL J31 OK ; OK ^######### % @w% ' UUUUUU?% Qw ( 6 DATA REQUIRED IN CELL D32 OK ; OK ^######### % w% ' UUUUUU?% R0 ( 6 8 U DATA REQUIRED IN CELL J32 OK ; OK ^######### % @w% ' ?% ( 6 @ U DATA REQUIRED IN CELL D33 OK ; OK ^######### % w% ' ?% R0 ( 6 H U DATA REQUIRED IN CELL J33 OK ; OK ! ^######### % ! @w% % ! Q % ! R ( 6 ! P U! DATA REQUIRED IN CELL D34 OK ; ! OK ! ^######### % ! w% % ! Q % ! Q( 6 ! X U! DATA REQUIRED IN CELL J34 OK ; ! OK " ^######### % " @w% ' " ?% " ( 6 " ` U" DATA REQUIRED IN CELL D35 OK ; " OK " ^######### % " w% ' " ?% " 0 ( 6 " h U" DATA REQUIRED IN CELL J35 OK ; " OK B @ 6 6 Pu ` ` ? ? P 6 u P 6 u P 6 u 6P 6 u P 6 u Z N B 0 * 0 < r 6 < $ H Z $ 6 6 N f < 6 ~ < 6 * x * 0 r x 6 * x 6 r 6 < y @ y y q y ' y y y y y y y y $ $ P P P P P P P P P P P "P P P =P :P P :P ;P P P P P "P P P P =P :P P :P 9P P P @P P P $P P P P =P :P P :P 9P P P @P P P $P P =P 9P (P 8P 9P P P P !P #P P P P +P ,P P P P -P P /P P 'P (P )P P )P P -P .P P P 0P P $P P 'P (P *P P *P P -P !P P P P $P P 'P (P *P P *P P -P !P P P P /P P 'P (P *P P *P (P P -P $P P 1P $P P !P 'P (P *P P *P (P P -P $P 'P (P *P P *P (P /P $P /P 'P (P *P P *P (P P -P P /P P $P /P 'P (P *P P *P P P -P .P P P P $P P $P /P 'P P -P !P P P P $P P 'P P -P !P P P P /P P P P 1P P !P 3P P P P P 4P P P P /P P $P P P P P P P P P P 5P /P P $P P P P P P P %P P P P /P P /P P *P %P P %P P P P !P $P ' /P /P P P P P P 4P P P -P P /P P $P 'P P P P P P -P .P P P 0P P $P P $P 'P P P P P P -P !P P P P $P P 'P P P P P P -P !P P P P /P P 'P P P P P P P -P $P P 1P $P P !P 'P P P P P P P -P $P 'P P *P P *P P /P $P 'P P %P P %P P P -P P /P P $P 'P P %P P %P P P -P .P P P P $P P $P 'P P -P !P P P P $P P 'P P -P !P P P P /P P P P 1P P !P P P P P P P P P P P P P P P P P P P P P P P P P P P P P P %P P P 7P P P P P P P P P %P P P 7P P P P *P %P P %P P P P P !P P P P +P ,P P P P -P P /P P 'P (P )P P )P P -P .P !P P 0P !P $P P 'P (P *P P *P P -P !P P !P $P P 'P (P *P P *P P -P !P P !P /P P 'P (P *P P *P P P -P $P P 1P $P P !P 'P (P *P P *P P P -P $P 'P (P *P P *P P /P $P 'P (P *P P *P P P -P P /P P 'P (P *P P *P P P -P .P !P P !P $P P 'P P -P !P P !P $P P 'P P -P !P P !P /P P P P 1P P !P 3P P P P P 4P P P P /P P $P P P P P P P :P ;P P P 1P /P P $P P P P P P P 9P P P !P /P P P *P %P P %P 9P P P P !P $P P P P P P P 4P P P -P P /P P $P 'P P P P P =P P -P .P !P P 0P !P $P P $P 'P P P P P =P P -P !P P !P $P P $P 'P P P P P =P P -P !P P !P /P P $P /P 'P P P P P =P P P -P $P P 1P $P P !P $P /P 'P P P P P =P P P -P $P $P /P 'P P *P P *P BP P /P $P /P $P /P 'P P %P P %P 9P P P -P P /P P $P /P $P /P 'P P %P P %P 9P P P -P .P !P P !P $P P $P /P $P /P 'P P -P !P P !P $P P $P /P 'P P -P !P P !P /P P $P /P P P 1P P !P P $P /P $ P $P /P $ P $P AA A A A A A A AA A A A A A A A A A A A A A A A A A A AA A A A A A A A AA ! A A A A A A A A A A A A A A A A AA A A A A A A AA ! A A A A A A A A A A A A A A A A AA A A A A A A A A AA ! A A A A A A A A A A A A A A A A B R @ : C A @ @ A A @ A E [ @ @ @ 6 E A @ A A @ A A A Q @M A A @ @ @, @M A @ A A @ A @ A A @Y [ A A @ A 0 E A @ A A @ A 2 B B a = / 1 ' d Default B B a = / 1 ' d Default B B N @ d 15 ppm S Precis _ , B @ B @ 15 ppm S Accura _ , , B @ B @ 500 ppm S Preci _ , , B @ B @ 500 ppm S Accur _ , , B @ B @ Ex 15 ppm S _ , , B @ B @ Ex 15 ppm Acc. _ , , B @ B @ ! Ex 500 ppm Pre _ " ! , , B @ " " # B @ " " $ % & Ex 500 ppm Acc _ ' & % , % , B @ ' ' ( B @ ' ' W 0 % Joe Sopata/DC/USEPA/US Joe Sopata/DC/USEPA/US 123 123 Property Doc Info Author Doc Info Comments Doc Info Editing Time Doc Info Keywords Doc Info Last Revisor Doc Info Object Doc Info Revisions Doc Info Revisions Count Doc Info Subject Doc Info Title M < O L L ZL M !M ZL L tL DM L 1M L L L L L nM L ]M L L L CMHdr M <