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Class II Ozone-Depleting Substances

Class II substances are listed in section 602 of the Clean Air Act, and comprise all HCFCs. All the class II substances and their isomers are regulated under the accelerated phaseout. These compounds are numbered according to the ASHRAE Standard 34 scheme.

The list of Class I substances (the CFCs) is here.

GWPs for selected non-ozone-depleting substances are provided in another table.

Why are there three values given for the ODPs and four values given for the GWPs?

The numbers in the “ODP-1” column are from Table 1-5 of The Scientific Assessment of Ozone Depletion, 2002, a report of the World Meteorological Association’s Global Ozone Research and Monitoring Project. The ODPs in the “ODP-1” column that were not in Table 1-5 of the 2002 report have not been updated since 1998 and are from The Scientific Assessment of Ozone Depletion, 1998. The “ODP-2” column numbers are from the Montreal Protocol, and the “ODP-3” column numbers are from 40 CFR Part 82, stratospheric ozone protection regulations required by title VI of the Clean Air Act amendments.

All GWP values represent global warming potential over a 100-year time horizon. The numbers in the “GWP-1” column are from Table 1-6 of The Scientific Assessment of Ozone Depletion, 2002, a report of the World Meteorological Association’s Global Ozone Research and Monitoring Project. The GWPs in the “GWP-1” column that were not provided in Table 1-6 of the 2002 report have not been updated since 1998 and are from The Scientific Assessment of Ozone Depletion, 1998. “GWP-2” column numbers are from the Intergovernmental Panel on Climate Change (IPCC Exit EPA ) Second Assessment Report: Climate Change 1995, “GWP-3” column numbers are from the IPCC Third Assessment Report: Climate Change 2001, and “GWP-4” column numbers are from 40 CFR Part 82, stratospheric ozone protection regulations required by title VI of the Clean Air Act amendments.

Under section 602, EPA was required to list in the Federal Register the GWPs for ozone-depleting substances. That list was published on January 19, 1996.

Blanks in the data indicate that the information was not shown in the original source.

Chemical Name Lifetime,
in years
ODP1 (WMO 20021) ODP2 (Montreal Protocol) ODP3 (40 CFR) GWP1 (WMO 2002) GWP2 (SAR) GWP3 (TAR) GWP4 (40 CFR) CAS Number
HCFC-21 (CHFCl2)
Dichlorofluoromethane
1.7 0.04 0.04   148   210   75-43-4
HCFC-22 (CHF2Cl)
Monochlorodifluoromethane
12.0 0.05 0.055 0.05 1780 1500 1700 1700 75-45-6
HCFC-31 (CH2FCl)
Monochlorofluoromethane
  0.02 0.02           593-70-4
HCFC-121 (C2HFCl4)
Tetrachlorofluoroethane
  0.0 1 - 0.04 0.01- 0.04           354-14-3
HCFC-122 (C2HF2Cl3)
Trichlorodifluoroethane
  0.02 - 0.08 0.02 - 0.08           354-21-2
HCFC-123 (C2HF3Cl2)
Dichlorotrifluoroethane
1.3 0.02 0.02 - 0.06 0.02 76 90 120 93 306-83-2
HCFC-124 (C2HF4Cl)
Monochlorotetrafluoroethane
5.8 0.02 0.02 - 0.04 0.02 599 470 620 480 2837-89-0
HCFC-131 (C2H2FCl3)
Trichlorofluoroethane
  0.007 - 0.05 0.007 - 0.05           359-28-4
HCFC-132b (C2H2F2Cl2)
Dichlorodifluoroethane
  0.008 - 0.05 0.008 - 0.05           1649-08-7
HCFC-133a (C2H2F3Cl)
Monochlorotrifluoroethane
  0.02 - 0.06 0.02 - 0.06           75-88-7
HCFC-141b (C2H3FCl2)
Dichlorofluoroethane
9.3 0.12 0.11 0.1 713   700 630 1717-00-6
HCFC-142b (C2H3F2Cl)
Monochlorodifluoroethane
17.9 0.07 0.065 0.06 2270 1800 2400 2000 75-68-3
HCFC-221 (C3HFCl6)
Hexachlorofluoropropane
  0.015 - 0.07 0.015 - 0.07           422-26-4
HCFC-222 (C3HF2Cl5)
Pentachlorodifluoropropane
  0.01 - 0.09 0.01 - 0.09           422-49-1
HCFC-223 (C3HF3Cl4)
Tetrachlorotrifluoropropane
  0.01 - 0.08 0.01 - 0.08           422-52-6
HCFC-224 (C3HF4Cl3)
Trichlorotetrafluoropropane
  0.01 - 0.09 0.01 - 0.09           422-54-8
HCFC-225ca (C3HF5Cl2)
Dichloropentafluoropropane
1.9 0.02 0.025   120   180 170 422-56-0
HCFC-225cb (C3HF5Cl2)
Dichloropentafluoropropane
5.8 0.03 0.033   586   620 530 507-55-1
HCFC-226 (C3HF6Cl)
Monochlorohexafluoropropane
  0.02 - 0.1 0.02 - 0.1           431-87-8
HCFC-231 (C3H2FCl5)
Pentachlorofluoropropane
  0.05 - 0.09 0.05 - 0.09           421-94-3
HCFC-232 (C3H2F2Cl4)
Tetrachlorodifluoropropane
  0.008 - 0.1 0.008 - 0.1           460-89-9
HCFC-233 (C3H2F3Cl3)
Trichlorotrifluoropropane
  0.007 - 0.23 0.007 - 0.23           7125-84-0
HCFC-234 (C3H2F4Cl2)
Dichlorotetrafluoropropane
  0.01 - 0.28 0.01 - 0.28           425-94-5
HCFC-235 (C3H2F5Cl)
Monochloropentafluoropropane
  0.03 - 0.52 0.03 - 0.52           460-92-4
HCFC-241 (C3H3FCl4)
Tetrachlorofluoropropane
  0.004 - 0.09 0.004 - 0.09           666-27-3
HCFC-242 (C3H3F2Cl3)
Trichlorodifluoropropane
  0.005 - 0.13 0.005 - 0.13           460-63-9
HCFC-243 (C3H3F3Cl2)
Dichlorotrifluoropropane
  0.007 - 0.12 0.007 - 0.12           460-69-5
HCFC-244 (C3H3F4Cl)
Monochlorotetrafluoropropane
  0.009 - 0.14 0.009 - 0.14            
HCFC-251 (C3H4FCl3)
Trichlorofluoropropane
  0.001 - 0.01 0.001 - 0.01           421-41-0
HCFC-252 (C3H4F2Cl2)
Dichlorodifluoropropane
  0.005 - 0.04 0.005 - 0.04           819-00-1
HCFC-253 (C3H4F3Cl)
Monochlorotrifluoropropane
  0.003 - 0.03 0.003 - 0.03           460-35-5
HCFC-261 (C3H5FCl2)
Dichlorofluoropropane
  0.002 - 0.02 0.002 - 0.02           420-97-3
HCFC-262 (C3H5F2Cl)
Monochlorodifluoropropane
  0.002 - 0.02 0.002 - 0.02           421-02-03
HCFC-271 (C3H6FCl)
Monochlorofluoropropane
  0.001 - 0.03 0.001 - 0.03           430-55-7

1 The Scientific Assessment of Ozone Depletion, 2002 updated a limited number of GWPs and ODPs (semiempirical values for all updated ODPs except CFC-114 and CFC-115, which are model-derived). All GWPs and ODPs that were not updated in 2002 are 1998 values that have not changed.

 

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