WPCS0 W.i,[$ָI.or%YŘfX>hثT{"rt1A I_ ֦$ JQ}PM?y^ d`>9Ֆi}GyEKMPъ4̭'d_*[r/[Y [иk*LV/-/B}nv=ń**/-.) aQˏ޶_B7}2=IR1FZBg{P,*8"A~ZF+~GMX[LJ 坤]4.HZjKBp)>2nTQ~]~ZI?HY)TU$,!n^_q[IP\a0G IC.w,&Hq r C-ӾPk:$e6a?{!T[tC5w 4">߄EғLJ 0  0 0q 0y 0k 0k 0~d 0~ 0` 07 0 0 0k 0  0 0Q 0 0 0 0 0 0. 0A 0T+U: %r 0z1 0  0= 0F 0P# 1s 0 1 0 0O{$E$^ $ 0O$# '% C2&fL&aN& B*b& B& D+&& 0O' 0E' AY.(dT({)V*d*P+, 1,T-nXd- 04.N..w.4.U> / 0PJ/ m/U./n/ hM0VV8Document[1]Document Style  @..  23  Ԁ     Ԉ V-8Document[2]Document Style 23  Ԁ   V=8Document[3]Document Style.. 23  Ԁ   V8Document[4]Document Style.. . V 8Document[5]Document Style0..V 8Document[6]Document Style8..V& 8Document[7]Document Style0..0` ..` V& 8Document[8]Document Style0..8` ..` l80:Technical[1]Technical Document Style  23  Ԁ     .. l-%:Technical[2]Technical Document Style 23  Ԁ   .. l*!:Technical[3]Technical Document Style 23  Ԁ   .. l&!:Technical[4]Technical Document Style 23  Ԁ   .. l/:Technical[5]Technical Document Style.. 23  Ԁ. l/:Technical[6]Technical Document Style.. 23  Ԁ. l/:Technical[7]Technical Document Style.. 23  Ԁ. l/:Technical[8]Technical Document Style.. 23  Ԁ. zS :Right Par[1]Right-Aligned Paragraph Numbers..23  Ԁ..0..zf :Right Par[2]Right-Aligned Paragraph Numbers..` ..` 23  Ԁ..0` ..` zy :Right Par[3]Right-Aligned Paragraph Numbers..` ..`  .. 23  Ԁ` ..` 0 .. z :Right Par[4]Right-Aligned Paragraph Numbers..` ..`  .. ..23  Ԁ .. 0..z :Right Par[5]Right-Aligned Paragraph Numbers..` ..`  .. ..h..h23  Ԁ..0h..hz :Right Par[6]Right-Aligned Paragraph Numbers..` ..`  .. ..h..h..23  Ԁh..h0..z :Right Par[7]Right-Aligned Paragraph Numbers..` ..`  .. ..h..h....23  Ԁ..0..z :Right Par[8]Right-Aligned Paragraph Numbers..` ..`  .. ..h..h....p..p23  Ԁ..0p..p<6X9`("Courier 10cpiX'    0 .   R& 8BibliogrphyBibliography0....fp2Doc InitInitialize Document StyleS "   I. 1. A. a.(1)(a) i) a)S !($0 ($0 0 (($0 0 0  A_ekqwDocumentDocument StyleI.1.A.a.(1)(a)i)a)jo4Tech InitInitialize Technical StyleS $   1 .1 .1 .1 .1 .1 .1 .1 S  CuyTechnicalTechnical Document Style11.11.1.11.1.1.11.1.1.1.11.1.1.1.1.11.1.1.1.1.1.11.1.1.1.1.1.1.1x?t2PleadingHeader for numbered pleading paper &  '/(   XXXXXXXXXXXX?0('*dE*??0('*dE*?HH1HH2HH3HH4HH5HH6HH7HH8HH910111213141516171819202122232425262728  .+('2/$ ?T!   Z%('2/$ ?T!   HP LaserJet 5/5M - EnhancedHPBXLA0nLH dTable_A&0 d d d'dxd Level 1 Level 2 Level 3 Level 4 Level 5('2/$ ?T!   ($ (    ) 2341M << deUUXX$WoXX;$s.X)QXXHMx1XXXXMcy1XXHXXMcy2XXXX M x2XXM:cy1XXHXXM:cy2 qFUNC{WSUBo~=~{MSUB{x1}~+~MSUB{cy1}~~MSUB{cy2}~~MSUB{x2}}OVER{MSUB{cy1}~~MSUB{cy2}}} 3/#   _-pP hxX- '' _ Eq.24A1 XX5VoXX950 X']XXFXXFWoXXkXXkDcXXXX}DU8o FFUNC{VSUBo~=~{WbarSUBo~DbarSUBc}OVERDbarSUBo} 3/#   _-pP hxX- '' _ Eq.24A2  CRight ParRight-Aligned Paragraph NumbersI.A.1.a.(1)(a)i)a)3|x<6X9`("Courier 10cpiXx6X@`7X@< 9(*Courier BoldiBoldXx 7X( T$  j%<( 9Z &Courier Regular((3 $ ?T!   U<6X9`(Courier d E '   _DX9XXX- ?T!   _-pP hxX-  H7D9DXXdd7@ METHOD24ADETERMINATIONOFVOLATILEMATTERCONTENT Z   @@44ANDDENSITYOFPUBLICATIONROTOGRAVUREINKSANDRELATEDPUBLICATIONROTOGRAVURECOATINGS  " ;1.0ScopeandApplication.    p 1.1_Analytes_.*q-. ddd Xdd Xdd X(#(#q,hdd", dd"+  //" d  p/_Analyte_ ./!  / ._CAS_ԀNo. J009!   p / `JVolatileorganiccompounds(_VOC_) 200!v 00 2No_CAS_Ԁnumberassigned1'%v   `  00 1 p 1.2Applicability.Thismethodisapplicableforthedeterminationofthe_VOC_Ԁcontentanddensityofsolventborne(solventreducible)publicationrotogravureinksandrelatedpublicationrotogravurecoatings.2.0SummaryofMethod. Z  p 2.1Separateproceduresareusedtodeterminethe_VOC_weightfractionanddensityoftheinkorrelatedcoatingandthedensityofthesolventintheinkorrelatedcoating.The_VOC_Ԁweightfractionisdeterminedbymeasuringtheweightlossofaknownsamplequantitywhichhasbeenheatedforaspecifiedlengthoftimeataspecifiedtemperature.Thedensityofboththeinkorrelatedcoatingandsolventaremeasuredbyastandardprocedure.Fromthisinformation,the_VOC_Ԁvolumefractioniscalculated.3.0Definitions.[Reserved] )#) 4.0Interferences.[Reserved] +`%+ H5.0Safety. ~-$'- _ p 5.1Disclaimer.Thismethodmayinvolvehazardousmaterials,operations,andequipment.Thistestmethoddoesnotpurporttoaddressallofthesafetyproblemsassociatedwithitsuse.Itistheresponsibilityoftheuserofthistestmethodtoestablishappropriatesafetyandhealthpracticesandtodeterminetheapplicabilityofregulatorylimitationspriortoperformingthistestmethod. p 5.2HazardousComponents.Someofthecompoundsthatmaybecontainedintheinksorrelatedcoatingsanalyzedbythismethodmaybeirritatingorcorrosivetotissuesormaybetoxic.Nearlyallarefirehazards.Appropriateprecautionscanbefoundinreferencedocuments,suchasReference6ofSection16.0.6.0EquipmentandSupplies.Thefollowingequipmentand N suppliesarerequiredforsampleanalysis: p 6.1WeighingDishes.Aluminumfoil,58mm(2.3in.)indiameterby18mm(0.7in.)high,withaflatbottom.Theremustbeatleastthreeweighingdishespersample. p 6.2DisposableSyringe.5ml. p 6.3AnalyticalBalance.Tomeasuretowithin0.1mg. p 6.4Oven.Vacuumovencapableofmaintainingatemperatureof1202$C(2484$F)andanabsolute n+%* pressureof51051mmHg(202in.Hg)for4hours. 2-&, Alternatively,aforceddraftovencapableofmaintainingatemperatureof1202$C(2484$F)for24hours.   p 6.5TheequipmentandsuppliesspecifiedinASTMD147560,80,or90(incorporatedbyreferenceGX9XXXԀsee60.17)#X9XXGX9#.  L _7.0ReagentsandStandards. j   p 7.1ThereagentsandstandardsspecifiedinASTMD147560,80,or90arerequired.8.0SampleCollection,Preservation,Storage,and P  Transport. b  p 8.1Followthesamplecollection,preservation,storage,andtransportproceduresdescribedinReference4ofSection16.0.9.0QualityControl.[Reserved] f  10.0CalibrationandStandardization.[Reserved] * 11.0AnalyticalProcedure.Additionalguidancecanbe  foundinReference5ofSection16.0. p 11.1_VOC_ԀWeightFraction.Shakeormixtheinkorrelatedcoatingsamplethoroughlytoassurethatallthesolidsarecompletelysuspended.Labelandweightothenearest0.1mgaweighingdishandrecordthisweight(Mx1). 'h!& Usinga5mlsyringe,withoutaneedle,extractanaliquotfromtheinkorrelatedcoatingsample.Weighthesyringeandaliquottothenearest0.1mgandrecordthisweight -&, (Mcy1).Transfer1to3gofthealiquottothe_tared_ Z weighingdish._Reweigh_Ԁthesyringeandremainingaliquottothenearest0.1mgandrecordthisweight(Mcy2).Heatthe   weighingdishwiththetransferredaliquotinavacuumovenatanabsolutepressureof51051mmHg(202in.Hg)andatemperatureof1202$C(2484$F)for4hours. .  Alternatively,heattheweighingdishwiththetransferredaliquotinaforceddraftovenatatemperatureof1202 \  $Cfor24hours.Aftertheweighingdishhascooled, z  _reweigh_Ԁittothenearest0.1mgandrecordtheweight(Mx2).Repeatthisproceduretwotimesforeachinkor  relatedcoatingsample,foratotalofthreesamples. p 11.2 InkorRelatedCoatingDensity.Determinethe 0 densityoftheinkorrelatedcoating(Dc)accordingtothe N procedureoutlinedinASTMD1475.Makeatotalofthreedeterminationsforeachinkorrelatedcoatingsample.Reporttheinkorrelatedcoatingdensityasthearithmeticaverage_()Dxx:c)_Ԁofthethreedeterminations. ^$"  p 11.3SolventDensity.Determinethedensityofthesolvent(Do)accordingtotheprocedureoutlinedinASTMD '!& 1475.Makeatotalofthreedeterminationsforeachinkorrelatedcoatingsample.Reportthesolventdensityasthearithmeticaverage()Dxx:o)ofthethreedeterminations. 2-&,  p 12.0CalculationsandDataAnalysis. Z  p 12.1_VOC_ԀWeightFraction.Foreachdetermination,calculatethevolatileorganiccontentweightfraction(_Wo_)  | usingthefollowingequation:5768QA=z  0 @Xdddddddd@E^ Nd @5_ ^    (#(#           (#(#  Makeatotalofthreedeterminations.Reportthe_VOC_Ԁweightfractionasthearithmeticaverage()Wxx:o)ofthethree n determinations. p 12.2_VOC_ԀVolumeFraction.Calculatethevolumefractionvolatileorganiccontent(Vo)usingthefollowing ` equation:5:9;QA=z  0 @Xdddddddd@EB idk@B_ B   (#(#           (#(#  13.0MethodPerformance.[Reserved] "4  14.0PollutionPrevention.[Reserved] R$" 15.0WasteManagement.[Reserved] &$ 16.0References. '!&  p 1.0 P StandardTestMethodforDensityofPaint,Varnish, )D#( Lacquer,andRelatedProducts.ASTMDesignationD1475.&-&,P (#P (# _ p 2.0 P Teleconversation.Wright,Chuck,InmontCorporation Z withReich,R.,A.,RadianCorporation.September25,1979,GravureInkAnalysis. P (#P (#  p 3.0 P _Teleconversation_.Oppenheimer,Robert,Gravure  L ResearchInstitutewithBurt,Rick,RadianCorporation,November5,1979,GravureInkAnalysis. P (#P (#  p 4.0 P StandardProcedureforCollectionofCoatingandInk   SamplesforAnalysisbyReferenceMethods24and24A.EPA340/191010.U.S.EnvironmentalProtectionAgency,StationarySourceComplianceDivision,Washington,D.C.September1991. P (#P (#  p 5.0 P StandardOperatingProcedureforAnalysisofCoating l andInkSamplesbyReferenceMethods24and24A.EPA340/191011.U.S.EnvironmentalProtectionAgency,StationarySourceComplianceDivision,Washington,D.C.September1991. P (#P (#  p 6.0 P HandbookofHazardousMaterials:Fire,Safety, "@  Health.AllianceofAmericanInsurers._Schaumberg_,IL.1983. P (#P (# 17.0Tables,Diagrams,Flowcharts,andValidationData. '!& [Reserved]