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( ( ) * + "+ - . 0 1 2 3 4 4 5! 5" 5$ 4% 4& 3' 2( 1( 5 6 6 6 5 5 4 3 2 0 / - , + * ) ) &) ( ( ( ( ) * + , - . / 0 1 2 3 4 5 5 A B B B B A @ ? > = < ; : 9 8 7 6 5 5 "4 4 4 5 5 6 7 8 9 ; < > ? @ A A B K K K J J I H G F D C A @ ? > > = "= = = > > ? @ A C D F G H I J J K S S S R R Q P O M L J I H G F F E &E E E F F G H I J K L M N O P Q R S S X X X W W V U T S R Q P O N M L K J J "J J K K L M N P Q R T U V W W X X u[ t[ rZ qZ pY oX oW nU nT nS oQ oP pO qN rN tM uM "uM wM xN yN zO {P {R |S |T |V {W {X zY yZ wZ v[ u[ U] S] R\ Q\ P[ OZ OX NW NV NT OS OR PQ QP SP TO UO &UO VO WP XP YQ ZR [S \T \U \V \W [X [Y ZZ Y[ X\ W] V] U] 5\ 4\ 3[ 2[ 1Z 0Y /X .W .V .U .T /S /R 0Q 1P 2O 3N 4N 5N "5N 6N 7O 9O :P ;Q ;R <S <U <V ;W ;Y :Z 9[ 8[ 7\ 5\ Z Z Y Y X W V U S R Q O N M M L L "L L M N N O Q R S U V W X Y Y Z Z V V U T T S Q P O M L K J I I H H "H I I J K L M O P Q S T T U V V V O N N M L K J H G F D C C B A A A "A B B C D E F H I K L M N N O O O G F F E D C B @ ? = < ; : : 9 9 9 &9 : ; < = > ? @ A B C D E F G G G G G < ; : 9 8 7 6 5 4 3 2 1 0 / . . . . . &/ / 0 1 2 3 4 5 6 7 8 9 : ; < < < < ; x/ w/ v. u- t, s+ s* s) s( t' t& u% v$ w# x" y" z" {" |# "}# ~# $ % & ( ) + , - . ~/ }/ {0 z0 x0 w/ Z! Y! X W W V V V W W X Y Z \ ] _ ` &` a b c d d d d d c b a `! _" ^" ]" \" [" Z! > = < ; : : : : : ; < = > ? @ A B C D "E F G G H H H G G F E D C A @ ? = # " ! !    ! ! " # $ % ' ( ) + "+ , - - . . . - - , + * ( ' % $ #                  &                                      "                                  "                                  &                                      "                 u t s q p n m l k k j j j k k l m &n o p q r s t u v w w x x x x w v v t Y X W V U T S R Q P P O O O O P Q Q S &S T U V W X Y [ [ \ ] ] ] ] \ \ [ Z Y z= y< y; y: y9 z8 z7 {5 |5 }4 ~3 3 3 3 4 4 5 6 7 "7 8 : ; = > ? @ @ A A A }@ |@ {? z> z= l k k k l l m n o p r s u v w x x &x y y y y x w! v" u# t# s$ r$ q$ p$ o# n" m! l l ` _ _ _ _ ` a b c d e f g h i j k l l "m m m l l k j i h f e c b a ` ` _ V V V W W X Y Z [ ] ^ ` a b c c d "d d d c c b a ` ^ ] [ Z Y X W W V N N N O O P Q R T U W X Y Z [ [ \ &\ \ \ \ [ Z Y X W V U T S R Q P O N N H H H H I J K L M N O P Q R S T U V V "V V U U T S R Q O N M K J J I H H D D E E~ F} G} H| I{ K{ L{ M| O| P} P~ Q R R "R R Q Q P O M L K I H G F E E D D Bb B` C_ C^ D] E\ G\ H[ I[ K[ L\ M\ N] O^ O` Pa Pb &Pb Pc Pd Oe Nf Mg Lh Ki Ji Ii Hi Gi Fh Eg Df Ce Bd Bc Bb BA B@ B? C> D= E< F; G: H: I: J: K: L; M< N= O> P? P@ PA "PA PB OC OE NF MG LG KH IH HH GG EG DF CE CD BC BA D! D E E F G H I K L M O P Q Q R R! "R! R# Q$ P% P& O' M' L( K( I( H' G& F& E% E# D" D! H H I J J K M N O Q R S T U U V V &V V U T S R Q P O N M L K J I H H H H N N O P Q R S T U V W X Y Z [ \ \ \ \ "\ [ [ Z Y X W U T R Q P O O N N N V W W X Y Z [ ] ^ ` a b c c d d d "d c c b a ` ^ ] [ Z Y X W W V V V _ ` ` a b c e f h i j k l l m m m &l l k j i h g f e d c b a ` _ _ _ _ ` l l m n o p q r s t u v w x y y y y x "x x w v u s r p o n m l l k k k l zf ze {d |c }c b b b c c d e f h i k l &l m n o o p p p ~p }o |n {n zl zk yj yi yh yg zf J I H G G F F F F G H H J K L M N O P &P R R S T T T T S S R Q P O N M L K J / - - , + + + + , , - . / 0 1 2 3 4 5 "6 7 8 8 9 9 9 8 8 7 6 5 3 2 0 / .                  &                                      "                                  "                                  &                                      "                 # $ % ' ( * + , - - . . . - - , + "+ ) ( ' % $ # " ! !    ! ! " # = ? @ A C D E F G G H H H G G F E &D C B A @ ? > = < ; : : : : : ; < = > Z [ \ ] ^ _ ` a b c d d d d d c b a ` "` _ ] \ Z Y X W W V V V W W X Y Z wt xs zs {s }t ~t u v w x z { } ~  ~ } &| { z y x w v u~ t} t| s{ sz sy sx tw uv vu wt xt h g g g g h i j k l m n o p q r s t t &u u u u u t s r q p o n m l k j i h g \ \ \ \ \ ] ^ _ ` a b c d e f g h i j "j j j i i h g f d c a ` _ ^ ] ] \ T T T U U V W X Z [ ] ^ _ ` a a b &b b b b a ` _ ^ ] \ [ Z Y X W V U T T N N N N O P Q R S T U V W X Y Z [ \ \ &\ \ \ [ [ Z Y X W V U T S R Q P O N N I I I J J K L M N O P Q R S T U V W W "W W V V U T R Q P N M L K J J I I 5G 7G 8H 9H :I ;J ;L <M <N <P ;Q ;R :S 9T 7T 6U 5U &5U 4U 3U 2T 1S 0R /Q /P .O .N .M .L /K 0J 1I 2H 3H 4G 5G UF VF WF XG YH ZI [J [K \L \M \N \O [P ZQ YR XS WS VT UT "UT TT SS QS PR OQ OP NO NM NL OK OI PH QG RG SF UF uH vH wI yI zJ {K {L |M |O |P {Q {S zT yU xU wV uV "uV tV rU qU pT oS oR nP nO nN oL oK pJ qI rI tH uH K K L L M N O Q R S U V W X X Y Y &Y Y X W V U T S R Q P O N M L K K K K Q Q R S T U V W X Y Z [ \ ] ^ _ _ _ _ "_ ^ ^ ] \ [ Z X W V T S S R Q Q Q X Y Y Z [ \ ] _ ` a c d d e f f f "f e e d c b ` _ ] \ [ Z Y Y X X X a b b c d e g h j k l m n n o o o &n n m l k j i h g f e d c b a a a a b n n o p q r s t u v w x y z { { { { z "z z y x w v t s q p o n n m m m n 1{ 2{ 3| 4} 4~ 5 5 5 4 4 3 2 1 0 . - + "+ * ) ( ( ' ' ' (~ )} )| *{ ,{ -z .z 0z 1{ N O P Q Q R R R Q P P O M L K I H &H G F E D D D D D E F G H I J K L M N i j k l m m m m m l k j i h g f e d c "b a ` ` _ _ _ ` ` a b c e f g i j                ~ } "} | { { z z z { | | }                        "                                  "                                  &                                      "                 ! " # % & ' ) * * + , , , + + * ) ") ( & % $ " !          ! ; < > ? @ B C D E E F F F E E D C &B A @ ? > = < ; : 9 8 8 8 8 8 9 : ; < X Y Z [ \ ] ^ _ ` a b b b b b a ` _ ^ " ^ ] [ Z X W V U U T T T U U V W X 'u (v (x (y '{ '| &} %~ $~ # !  ~ ~ } | { "{ y x v u t s r r q !q #q $r %r &s 't 'u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`S q      ! < V o    i P 6      ! l$ M% /$ !      d J 1    o V < !      |q {S |4       j P 7    1 J d       / M l       6 P i    7 P j       4 &S R Q P N N M L L L L !M "M $N $O %P &Q &R &S %q %r $s $t #v "v !w x x x x w w v u t s r q "q o n m l k k j j j !k "k #l $m $n %p %q " " ! !              &              ! " " " "                    "                                  "                                  &                                      "                 $ % & ' ' ( ( ( ' ' & % $ " !   "              ! # $ ? @ A B B C C C B A A @ > = < : 9 &9 8 7 6 5 5 5 5 6 6 7 8 9 : ; < = > ? Y Z [ \ ] ] ] ] \ \ [ Z Y X W V U T S "R Q P P O O O P P Q R S U V X Y Z s t u u v v v u u t s r p o m l k &k j i h h h h h i j k l m n o p q r s                    "                                  "                      ~ } | { z z y y y z { { &| } ~                 m l k j i h g f e d c b b b b b c d e "e f h i k l m n o o p p p o o n m T S Q P N M L K J J I I I J J K L "L N O P R S T U V V W W W V V U T : 8 7 6 4 3 2 1 0 0 / / / 0 0 1 2 "3 4 6 7 8 : ; ; < = = = < < ; : 9                  "       ! ! " " " ! !                     &                                      "                                  "                 # # # " " !            &               ! " # # ( ( ( ( ' & % $ # " !         "        ! " $ % & ' ' ( ( l+ k+ i* h* g) f( f' e& e$ e# f! f g h i j l &l m n o p q r! r" s# s$ s% s& r' q( q) o* n* m+ l+ M, L, K, J+ I* H* G( G' F& F% F$ F# G" H! H J K L M &M N O P R R! S" T# T$ T% T& S' S( R* Q* P+ O, N, M, /+ .+ -* ,* *) *( )' (& (% ($ (# )" )! * + , - . / "/ 1 2 3 4 5 5! 6# 6$ 6& 5' 5( 4) 3* 2* 0+ /+ ( ( ' ' & % $ " !         &        ! " # $ % & ' ( ( ( ( # # " !                "           ! " " # # #                  "                                  &                                      "                 } { z y y x x x y y z { | }    "               } | a ` _ ^ ^ ] ] ] ^ _ _ ` b c d f g "h i j j k k k j j i h g f d c b ` F E D D C C C D D E F G H J K L N "N O P P Q Q Q P P O N M L J I G F - , + + * * * + + , - . / 1 2 4 5 &5 6 7 8 8 8 8 8 7 6 5 4 3 2 1 0 / . -                    "   ! ! !                             "                                  &                   s r q p o n m l k j i h h h h h i j k "k l m o p r s t u u v v v u u t s Z Y X V U S R Q P P O O O P P Q R &S T U V W X Y Z [ \ \ ] ] ] ] \ [ Z Y ? > = < ; : 9 8 7 6 6 5 5 5 5 6 7 8 9 "9 : < = > @ A A B C C C B B A @ ? $ # !               "  ! " $ % & ' ' ( ( ( ' ' & % $                  &                                      "                                  "                 } } } ~ ~             &                ~ } } x x x x y z { | } ~          "         ~ | { z y y x x uq up vn vm wl xk yk zj |j }j k k l m n o q &q r s t u v w ~w }x |x {x zx yw xv wv vt vs ur uq tS tR tQ uP vO vN xM yM zL {L |L }L ~M N N P Q R S &S T U V X X ~Y }Z |Z {Z zZ yY xY vX vW uV tU tT tS u4 u3 v2 v1 w/ x/ y. z- {- |- }- ~. . / 0 1 2 3 4 "4 6 7 8 9 : : }; |; z; y: x: w9 v8 v7 u5 u4 x x y y z { | ~          &         ~ } | { z y x x x x } } ~                 "            ~ ~ } } }                  "                                  &                                      "                      ~ ~ ~          "                 g f e d d c c c d e e f h i j l m &m n o p q q q q p p o n m l k j i h g M L K J I I I I J J K L M N O P Q R S "T U V V W W W V V U T S Q P N M L 3 2 1 1 0 0 0 1 1 2 3 4 6 7 9 : ; &; < = = > > > > = < ; : 9 8 7 6 5 4 3                 ! " # "$ % % & & & % % $ # " !                       "                            ! ! !    &                   - . / 0 1 2 3 4 5 6 7 8 8 8 8 8 7 6 5 "5 4 3 1 0 . - , + + * * * + + , - F G H J K M N O P P Q Q Q P P O N &M L K J I H G F E D D C C C C D E F G a b c d e f g h i j j k k k k j i h g "g f d c b ` _ _ ^ ] ] ] ^ ^ _ ` a | }                "   ~ | { z y y x x x y y z { |                  &                                      "                                  "                                  &                   ~ ~ ~ ~                "               ~ ~ /{ 0{ 2| 3| 4} 5~ 5 6 6 6 5 5 4 3 2 1 / &/ . - , + * ) ) ( ( ( ( ) *~ *} ,| -| .{ /{ Mz Nz Oz P{ Q| R| S~ S T T T T S R R P O N M &M L K J H H G F F F F G G~ H| I| J{ Kz Lz Mz l{ m{ n| o| q} q~ r s s s s r r q p o n m l "l j i h g f f e e e f f~ g} h| i| k{ l{ ~ ~                &               ~ ~ ~ ~                    "                                  "                                  &                                      "                    ! ! " " " ! !        "                 9 : ; < < = = = < ; ; : 8 7 6 4 3 &3 2 1 0 / / / / 0 0 1 2 3 4 5 6 7 8 9 S T U V W W W W V V U T S R Q P O N M "L K J J I I I J J K L M O P R S T m n o o p p p o o n m l j i g f e &e d c b b b b b c d e f g h i j k l m                 ~ } | "{ { z y y y z z { | } ~                       "                      ! " # $ % % & & & % % $ &# " !                 3 4 5 6 7 8 9 : ; < = > > > > = = < ; "; : 9 7 6 4 3 2 1 1 0 0 0 1 1 2 3 L M N P Q S T U V V W W W V V U T &S R Q P O N M L K J J I I I I J K L M g h i j k l m n o p p q q q q p o n m "m l j i h f e e d c c c d d e f g                  "         ~ ~ ~                       &                                      "                                  "                                  &                   " " " " !               "             ! ! " " %4 %5 $7 $8 #9 ": !: ; ; ; : : 9 8 7 6 4 &4 3 2 1 0 / . . - - - - !. "/ #/ $1 $2 %3 %4 &S &T &U %V $W $X "Y !Y Z Z Z Z Y X X V U T S @2S c s        u e U E 5 %        s c S C 3 #       % 5 E U e u       # 3 C "S R Q O N M M L L L M M N O P Q S c d e g h i i j j j i i h g f e c &b a ` _ ^ ] \ \ \ \ \ ] ^ _ ` a b c d t u v w x y z z z z z y x w v u t s r &q p o n m m l l l l m n o p q r s t u                    " ~ } | | { { { | | } ~                       "                                  &                                      "                                  "                                  &                            ~ } } } } } ~    &                   w v u t s r q p o o n n n n o p q r s "t u w x y z { { | | | { { z y x v f e c b a ` _ _ ^ ^ ^ _ _ ` a b d "e f g i j j k l l l k k j i h g e U T S Q P P O N N N O O P Q R S U &U V W X Y Z [ \ \ \ \ \ [ Z Y X W V U E D C B A @ ? > > > > > ? @ A B C D E "E G H I J K K L L L K J J I G F E 5 3 2 1 0 / / . . . / 0 0 1 3 4 5 "6 8 9 : ; ; < < < ; ; : 9 8 7 5 4 $ " !          ! " # % & &' ( ) * + , , , , + + * ) ( ' & % $ #                    &                                      "                                   "                                  &                                      "                                  "                      ~ } | | { { { | | } ~  &                   u t s r q p o n m l l l l m m n o p q &r s t u v w x y z z z z z y x w v u t d c b a ` _ ^ ] \ \ \ \ \ ] ^ _ ` a b "c e f g h i i j j j i i h g e d c S Q P O N M M L L L M M N O Q R S "S T U W X Y Y Z Z Z Y Y X W V U S C B A ? > = = < < < = = > ? @ A C &D E F G H I J J J J J I H G F E D C B 2 1 0 / . - , , , , , - . / 0 1 2 3 4 "5 6 7 8 9 9 : : : 9 8 8 7 5 4 3 1 !             ! " # % "& ' ( ) ) * * * ) ) ( ' % $ # !                   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" $ 4 5 7 8 9 : ; ; < < < ; ; : 9 8 6 "5 4 3 1 0 0 / . . . / / 0 1 2 3 5 E F G I J J K L L L K K J I H G E &E D C B A @ ? > > > > > ? @ A B C D E U V X Y Z [ [ \ \ \ \ \ [ [ Z Y X V U "U S R Q P O O N N N O P P Q S T U e g h i j k k l l l k j j i g f e "d b a ` _ _ ^ ^ ^ _ _ ` a b c e f v x y z { { | | | { { z y x w u t &s r q p o n n n n o o p q r s t u v w                    &   ~ } } } } } ~                             "                                  "                                  "                                  "                                  "                  ! # $ % ' ( ) ) * * * ) ) ( ' & "% # " !             ! 1 3 4 5 7 8 8 9 : : : 9 9 8 7 6 5 &4 3 2 1 0 / . - , , , , , - . / 0 1 2 B C D E F G H I J J J J J I H G F E D "C A @ ? > = = < < < = = > ? A B C S U V W X Y Y Z Z Z Y Y X W U T S  pM   G%2`HelveticaG Pump1`f$f$1&     f$ g$ i$ j$ k$ l$l$m$m$m$m$m$l$l$k$j$i$g$f$&m$m$m$l$k$j$i$h$g$f$e$d$c$b$a$`$_$_$_$_$_$_$`$a$b$c$d$e$f$g$h$i$j$k$l$m$m$m$&f$g$h$i$j$k$l$m$m$m$m$m$l$k$j$i$h$g$f$&  $|    G%2`HelveticaG Organic  $    G%2`HelveticaG Analyzer j #    G%2`HelveticaG and  $j    G%2`HelveticaG Recorder J   G%2`HelveticaG Heated J   G%2`HelveticaG Sample p   G%2`HelveticaG Line+  PM +P:;;<<<;;:986532106 , +? v | +P6. >: +%^  g +Pb* n0  @ ;    G%2`HelveticaG Particulate ! t    G%2`HelveticaG Filter     G%2`HelveticaG Calibration s      G%2`HelveticaG Valve8FIG25A-1.WPG 5~#  _9% pP hx(#',81X9+XdYXXXFigure25A1.OrganicConcentrationMeasurementSystem.  CRight ParRight-Aligned Paragraph NumbersI.A.1.a.(1)(a)i)a)3|x <6X9`("Courier 10cpiXx6X@8;X@< 9(*Courier 10cpiBoldXx B;X($<( 9Z &Courier Regular E{_D E  R}j' (| <6X9`(CourierAcrobat PDFWriter 3.0,,,,,,,,0U(3$ ?!   X h'  _@XXXX ?!  _9% pP hx(#',81X9    l8Xdd8 METHOD25ADETERMINATIONOFTOTALGASEOUSORGANIC L CONCENTRATIONUSINGAFLAMEIONIZATIONANALYZER  ,   $ DXpP $1.0ScopeandApplication.   1.1_Analytes_.*-. ddd Xdd Xdd X(#(#,` dd ,` dd ,` dd +  //" H  p/_Analyte_ 0/# / 0_CAS_ԀNo. 0/#  / 0Sensitivity L00;#   p / (LTotalOrganicCompounds 400#  00 4N/A 400#L 00 4<2%ofspan3)'L  (  00 3 1.2Applicability.Thismethodisapplicableforthedeterminationoftotalgaseousorganicconcentrationofvaporsconsistingprimarilyofalkanes,_alkenes_,and/or_arenes_Ԁ(aromatichydrocarbons).Theconcentrationisexpressedintermsofpropane(orotherappropriateorganiccalibrationgas)orintermsofcarbon. 1.3 DataQualityObjectives.Adherencetothe | requirementsofthismethodwillenhancethequalityofthedataobtainedfromairpollutantsamplingmethods.2.0SummaryofMethod. t!  2.1Agassampleisextractedfromthesourcethroughaheatedsamplelineandglassfiberfiltertoaflameionizationanalyzer(FIA).Resultsarereportedasvolumeconcentrationequivalentsofthecalibrationgasorascarbonequivalents.l3.0Definitions. )|#-  3.1Calibrationdriftmeansthedifferenceinthe +<%/ measurementsystemresponsetoamidlevelcalibrationgas H-&1 _beforeandafterastatedperiodofoperationduringwhichnounscheduledmaintenance,repair,oradjustmenttookplace. 3.2Calibrationerrormeansthedifferencebetween D  thegasconcentrationindicatedbythemeasurementsystemandtheknowconcentrationofthecalibrationgas. 3.3Calibrationgasmeansaknownconcentrationofa T  gasinanappropriatediluentgas. 3.4Measurementsystemmeansthetotalequipment p  requiredforthedeterminationofthegasconcentration.Thesystemconsistsofthefollowingmajorsubsystems: 3.4.1Sampleinterfacemeansthatportionofasystem  usedforoneormoreofthefollowing:sampleacquisition,sampletransportation,sampleconditioning,orprotectionoftheanalyzer(s)fromtheeffectsofthestackeffluent. 3.4.2Organicanalyzermeansthatportionofthe 8 measurementsystemthatsensesthegastobemeasuredandgeneratesanoutputproportionaltoitsconcentration. 3.5Responsetimemeansthetimeintervalfromastep $H$ changeinpollutantconcentrationattheinlettotheemissionmeasurementsystemtothetimeatwhich95percentofthecorrespondingfinalvalueisreachedasdisplayedon therecorder. L+%,  3.6SpanValuemeanstheupperlimitofagas L  concentrationmeasurementrangethatisspecifiedforaffectedsourcecategoriesintheapplicablepartoftheregulations.Thespanvalueisestablishedintheapplicableregulationandisusually1.5to2.5timestheapplicableemissionlimit.Ifnospanvalueisprovided,useaspanvalueequivalentto1.5to2.5timestheexpectedconcentration.Forconvenience,thespanvalueshouldcorrespondto100percentoftherecorderscale. 3.7Zerodriftmeansthedifferenceinthe L measurementsystemresponsetoazerolevelcalibrationgasbeforeorafterastatedperiodofoperationduringwhichnounscheduledmaintenance,repair,oradjustmenttookplace.4.0Interferences.[Reserved]  5.0Safety. x  5.1Disclaimer.Thismethodmayinvolvehazardousmaterials,operations,andequipment.Thistestmethodmaynotaddressallofthesafetyproblemsassociatedwithitsuse.Itistheresponsibilityoftheuserofthistestmethodtoestablishappropriatesafetyandhealthpracticesanddeterminetheapplicabilityofregulatorylimitationspriortoperformingthistestmethod.Theanalyzerusersmanualshouldbeconsultedforspecificprecautionstobetakenwithregardtotheanalyticalprocedure. ,x&.  5.2ExplosiveAtmosphere.Thismethodisoftenappliedinhighlyexplosiveareas.Cautionandcareshouldbeexercisedinchoiceofequipmentandinstallation.6.0EquipmentandSupplies D   6.1MeasurementSystem.Anymeasurementsystemfortotalorganicconcentrationthatmeetsthespecificationsofthismethod.AschematicofanacceptablemeasurementsystemisshowninFigure25A1.Allsamplingcomponentsleadingtotheanalyzershallbeheated>110$C(220$F) X  throughoutthesamplingperiod,unlesssafetyreasonsarecited(Section5.2)Theessentialcomponentsofthemeasurementsystemaredescribedbelow: 6.1.1OrganicConcentrationAnalyzer.Aflameionizationanalyzer(FIA)capableofmeetingorexceedingthespecificationsofthismethod.Theflameionizationdetectorblockshallbeheated>120$C(250$F). <  6.1.2SampleProbe.Stainlesssteel,orequivalent,threeholeraketype.Sampleholesshallbe4mm(0.16in.)indiameterorsmallerandlocatedat16.7,50,and83.3percentoftheequivalentstackdiameter.Alternatively,asingleopeningprobemaybeusedsothatagassampleiscollectedfromthecentrallylocated10percentareaofthe stackcross_Ԅsection. *$,  6.1.3HeatedSampleLine.StainlesssteelorTeflon tubingtotransportthesamplegastotheanalyzer.Thesamplelineshouldbeheated(110$C)topreventany  P condensation. 6.1.4CalibrationValveAssembly.Athreewayvalveassemblytodirectthezeroandcalibrationgasestotheanalyzersisrecommended.Othermethods,suchasquickconnectlines,toroutecalibrationgastotheanalyzersareapplicable. 6.1.5ParticulateFilter.Aninstackoranoutofstackglassfiberfilterisrecommendedifexhaustgasparticulateloadingissignificant.Anoutofstackfiltershouldbeheatedtopreventanycondensation. 6.1.6Recorder.Astripchartrecorder,analogcomputer,ordigitalrecorderforrecordingmeasurementdata.Theminimumdatarecordingrequirementisonemeasurementvalueperminute.7.0ReagentsandStandards. t"("  7.1CalibrationGases.Thecalibrationgasesforthegasanalyzershallbepropaneinairorpropaneinnitrogen.Alternatively,organiccompoundsotherthanpropanecanbeused;theappropriatecorrectionsforresponsefactormustbemade.CalibrationgasesshallbepreparedinaccordancewiththeprocedurelistedinCitation2ofSection16. |,0&. Additionally,themanufacturerofthecylindershouldprovidearecommendedshelflifeforeachcalibrationgascylinderoverwhichtheconcentrationdoesnotchangemorethan2percentfromthecertifiedvalue.Forcalibrationgasvaluesnotgenerallyavailable(i.e.,_organics_Ԁbetween1   and10percentbyvolume),alternativemethodsforpreparingcalibrationgasmixtures,suchasdilutionsystems(TestMethod205,40_CFR_ԀPart51,AppendixM),maybeusedwithpriorapprovaloftheAdministrator. 7.1.1Fuel.A40percentH2or/60percentN2orH e E e     gas L mixtureisrecommendedtoavoidanoxygensynergismeffectthatreportedlyoccurswhenoxygenconcentrationvariessignificantlyfromameanvalue. 7.1.2ZeroGas.Highpurityairwithlessthan0.1partpermillionbyvolume(_ppmv_)oforganicmaterial(propaneorcarbonequivalent)orlessthan0.1percentofthespanvalue,whicheverisgreater. 7.1.3LowlevelCalibrationGas.Anorganiccalibrationgaswithaconcentrationequivalentto25to35percentoftheapplicablespanvalue. 7.1.4MidlevelCalibrationGas.Anorganiccalibrationgaswithaconcentrationequivalentto45to55 percentoftheapplicablespanvalue. *$, _ 7.1.5HighlevelCalibrationGas.Anorganic calibrationgaswithaconcentrationequivalentto80to90percentoftheapplicablespanvalue.8.0SampleCollection,Preservation,Storage,and D  Transport.    8.1SelectionofSamplingSite.Thelocationofthesamplingsiteisgenerallyspecifiedbytheapplicableregulationorpurposeofthetest(i.e.,exhauststack,inletline,etc.).ThesampleportshallbelocatedtomeetthetestingrequirementsofMethod1. 8.2LocationofSampleProbe.Installthesampleprobesothattheprobeiscentrallylocatedinthestack,pipe,orductandissealedtightlyatthestackportconnection. 8.3MeasurementSystemPreparation.Priortotheemissiontest,assemblethemeasurementsystembyfollowingthemanufacturer'swritteninstructionsforpreparingsampleinterfaceandtheorganicanalyzer.Makethesystemoperable(Section10.1). 8.4CalibrationErrorTest.Immediatelypriortothetestseries(within2hoursofthestartofthetest),introducezerogasandhighlevelcalibrationgasatthecalibrationvalveassembly.Adjusttheanalyzeroutputtotheappropriatelevels,ifnecessary.Calculatethe ,H&. predictedresponseforthelowlevelandmidlevelgasesbasedonalinearresponselinebetweenthezeroandhighlevelresponse.Thenintroducelowlevelandmidlevelcalibrationgasessuccessivelytothemeasurementsystem.Recordtheanalyzerresponsesforlowlevelandmidlevelcalibrationgasesanddeterminethedifferencesbetweenthemeasurementsystemresponsesandthepredictedresponses.Thesedifferencesmustbelessthan5percentoftherespectivecalibrationgasvalue.Ifnot,themeasurementsystemisnotacceptableandmustbereplacedorrepairedpriortotesting.Noadjustmentstothemeasurementsystemshallbeconductedafterthecalibrationandbeforethedriftcheck(Section8.6.2).Ifadjustmentsarenecessarybeforethecompletionofthetestseries,performthedriftcheckspriortotherequiredadjustmentsandrepeatthecalibrationfollowingtheadjustments.Ifmultipleelectronicrangesaretobeused,eachadditionalrangemustbecheckedwithamidlevelcalibrationgastoverifythemultiplicationfactor. 8.5ResponseTimeTest.Introducezerogasintothemeasurementsystematthecalibrationvalveassembly.Whenthesystemoutputhasstabilized,switchquicklytothehighlevelcalibrationgas.Recordthetimefromthe concentrationchangetothemeasurementsystemresponse d,&. equivalentto95percentofthestepchange.Repeatthetestthreetimesandaveragetheresults.   8.6EmissionMeasurementTestProcedure. 8.6.1OrganicMeasurement.Beginsamplingatthestartofthetestperiod,recordingtimeandanyrequiredprocessinformationasappropriate.Inparticulate,noteontherecordingchart,periodsofprocessinterruptionorcyclicoperation. 8.6.2DriftDetermination.Immediatelyfollowingthecompletionofthetestperiodandhourlyduringthetestperiod,reintroducethezeroandmidlevelcalibrationgases,oneatatime,tothemeasurementsystematthecalibrationvalveassembly.(Makenoadjustmentstothemeasurementsystemuntilboththezeroandcalibrationdriftchecksaremade.)Recordtheanalyzerresponse.Ifthedriftvaluesexceedthespecifiedlimits,invalidatethetestresultsprecedingthecheckandrepeatthetestfollowingcorrectionstothemeasurementsystem.Alternatively,recalibratethetestmeasurementsystemasinSection8.4andreporttheresultsusingbothsetsofcalibrationdata(i.e.,datadeterminedpriortothetestperiodanddatadeterminedfollowingthetestperiod). NOTE: Noteontherecordingchartperiodsofprocess *p$, interruptionorcyclicoperation. |,0&. 9.0QualityControl L *12 dd` dd ` ` dd ` ` dd ` -.(#(#,Ldd ,| dd , dd +  3/0"  H3MethodSection =/0,!| 0"/0 =QualityControlMeasure =/0,!| 0"/0 =Effect Q/@,\"  H /0 xQ8.4 4/# / 4Zeroandcalibrationdrifttests. 4/# ` / 4Ensuresthatbiasintroducedbydriftinthemeasurementsystemoutputduringtherunisnogreaterthan3percentofspan.3)'  x0   / 310.0CalibrationandStandardization. \   10.1FIAequipmentcanbecalibratedforalmostanyrangeoftotalorganicconcentrations.Forhighconcentrationsoforganics(>1.0percentbyvolumeaspropane),modificationstomostcommonlyavailableanalyzersarenecessary.Oneacceptedmethodofequipmentmodificationistodecreasethesizeofthesampletotheanalyzerthroughtheuseofasmallerdiametersamplecapillary.Directandcontinuousmeasurementoforganicconcentrationisanecessaryconsiderationwhendetermininganymodificationdesign.11.0AnalyticalProcedure. #(  Thesamplecollectionandanalysisareconcurrentforthismethod(seeSection8.0).12.0CalculationsandDataAnalysis. )".  12.1Determinetheaverageorganicconcentrationintermsofppmvaspropaneorothercalibrationgas.The p,$&2 averageshallbedeterminedbyintegrationoftheoutputrecordingovertheperiodspecifiedintheapplicableregulation.Ifresultsarerequiredintermsofppmvascarbon,adjustmeasuredconcentrationsusingEquation25A1.@'Cc=KCmeasB(# Eq.25A1     where: Cc =Organicconcentrationascarbon,ppmv. T   Cmeas =Organicconcentrationasmeasured,ppmv.    K =Carbonequivalentcorrectionfactor. X    =2forethane.  =3forpropane.  =4forbutane.  =Appropriateresponsefactorforotherorganic  calibrationgases.    13.0MethodPerformance. H  13.1MeasurementSystemPerformanceSpecifications. 13.1.1ZeroDrift.Lessthan3percentofthespanvalue. 13.1.2CalibrationDrift.Lessthan3percentofspanvalue. 13.1.3CalibrationError.Lessthan5percentofthecalibrationgasvalue.14.0PollutionPrevention.[Reserved] *$, 15.0WasteManagement.[Reserved] ,`&. 16.0References. L  1.MeasurementofVolatileOrganicCompoundsGuidelineSeries.U.S.EnvironmentalProtectionAgency.ResearchTrianglePark,NC.PublicationNo.EPA450/278041.June1978.p.4654. 2.DXXXXEPATraceabilityProtocolforAssayand `  CertificationofGaseousCalibrationStandards.U.S.EnvironmentalProtectionAgency,QualityAssuranceandTechnicalSupportDivision.ResearchTrianglePark,N.C.September1993.#XXXDXC# L  3.GasolineVaporEmissionLaboratoryEvaluationPart2.U.S.EnvironmentalProtectionAgency,OfficeofAirQualityPlanningandStandards.ResearchTrianglePark,NC.EMBReportNo.75GAS6.August1975.17.0Tables,Diagrams,Flowcharts,andValidation_Data.  H 79:XHDzl  &`o$3333Z@@@EL ' 9' @)   (#(#                                                                                                                                          _        .'0