Aquatic Life Criteria - Copper
What is copper?
Copper is an abundant trace element that occurs naturally in the Earth’s crust and surface waters. Copper can be found as a pure metal in nature and has a high thermal and electrical conductivity. Copper compounds are generally found as copper (II) salts.
How is copper used?
Copper can be produced through mining activities. A few of the industries that rely on copper, and copper products are: for fabricated metal products, electric equipment, construction, and the leather and leather products industry.
How does copper affect aquatic life?
Copper is an essential nutrient at low concentrations, but is toxic to aquatic organisms at higher concentrations. In addition to acute effects such as mortality, chronic exposure to copper can lead to adverse effects on survival, growth, reproduction as well as alterations of brain function, enzyme activity, blood chemistry, and metabolism.
2007 Freshwater Copper Criteria Update
EPA issued a revised national recommended freshwater aquatic life criterion for copper (Aquatic Life Ambient Freshwater Quality Criteria—Copper 2007 Revision). As a companion to the criteria document, EPA has also released documents to supplement training materials and help states, tribes, permittees, and other interested stakeholders on implementing the nationally recommended criteria.
- Aquatic Life Ambient Freshwater Quality Criteria for Copper - 2007 Revision
- Fact Sheet: Aquatic Life Ambient Freshwater Quality Criteria for Copper - 2007 Revision
- Federal Register Notice: Aquatic Life Ambient Freshwater Quality Criteria for Copper - 2007 Revision (PDF)(3 pp, 88 K, About PDF) (February 22, 2007)
- Supplementary Training Materials about the Ambient Water Quality Criteria for Copper
- Supplementary information relevant to assessing data needed for inputs to the BLM - Spatial Trends in Water Chemistry and the Biotic Ligand Model
- For a copy of the 2007 BLM file please contact Luis Cruz, PhD at firstname.lastname@example.org
Note: This does not replace EPA's guidance materials on implementing the BLM.
2003 Draft Copper Criteria Update
EPA has published a draft document, 2003 Draft Update of Ambient Water Quality Criteria for Copper (EPA-822-R-03-026), containing updated freshwater and saltwater aquatic life criteria for copper. These criteria revisions are based in part on new data that have become available since EPA's last comprehensive criteria updates for copper. In addition to incorporating new data, the freshwater criteria also incorporate the use of the biotic ligand model (BLM) in the criteria derivation procedures.
- Fact Sheet: 2003 Draft Updated Aquatic Life Copper Criteria
- Federal Register Notice: Draft Aquatic Life Criteria Document for Copper and Request for Scientific Views (December 31, 2003)
- Background materials available at Regulations.gov using Docket No. EPA-HQ-OW-2003-0079
- 2003 Biotic ligand model (BLM) (zip)(3 pp, 4 MB)
- 2003 Draft Update of Ambient Water Quality Criteria for Copper
Related Technical Documents
Draft Technical Support Document: Recommended Estimates for Missing Water Quality Parameters for BLM
This draft technical support document provides recommendations for default values for water quality parameters that can be used in the Freshwater Copper BLM when data are lacking. The document also describes data analysis approaches used to develop these recommendations. Following closure of the public comment period on April 18, 2016, EPA will consider the comments, revise the document, as appropriate, and then publish a final technical support document that will serve as a source of information for states, tribes, territories, and other stakeholders.
- Extension of Public Comment Period for the Draft Technical Support Document: Recommended Estimates for Missing Water Quality Parameters for Application in EPA's Biotic Ligand Model (March 10, 2016)
- Federal Register Notice: Draft Technical Support Document: Recommended Estimates for Missing Water Quality Parameters for Application in EPA’s Biotic Ligand Model (February 16, 2016)
- Draft Technical Support Document: Recommended Estimates for Missing Water Quality Parameters for Biotic Ligand Model
- View public comments and other supporting documents on regulations.gov by searching for Docket Number EPA-HQ-OW-2015-0469
Streamlined Water-Effect Ratio Procedure for Discharges of Copper
This document presents a Streamlined Procedure for determining site-specific values for a Water-Effect Ratio (WER), a criteria adjustment factor accounting for the effect of site-specific water characteristics on pollutant bioavailability and toxicity to aquatic life. This procedure is only recommended for copper and in situations where copper concentrations are elevated primarily by continuous point source effluents.
The document is intended to complement the 1994 Interim Guidance on Determination and Use of Water-Effect Ratios for Metals (EPA-823-B-94-001). The design of the Streamlined Procedure is intended as a more efficient approach for generating the information needed to make a pollution control decision.